O-2-Naphthyl chlorothioformate

Base Information

• Chemical Name: O-2-Naphthyl chlorothioformate
• CAS No.: 10506-37-3
• Molecular Formula: C11H7ClOS
• Molecular Weight: 222.695
• Hs Code.: 2930909090
• European Community (EC) Number: 234-037-0
• UNII: T6L7YU9JEP
• DSSTox Substance ID: DTXSID20146934
• Nikkaji Number: J28.874H
• Wikidata: Q72493732
• Mol file: 10506-37-3.mol

Synonyms:10506-37-3;O-2-Naphthyl chlorothioformate;O-naphthalen-2-yl chloromethanethioate;naphthalen-2-yl chloromethanethioate;C11H7ClOS;EINECS 234-037-0;O-Naphthalen-2-yl Chlorothioformate;O-(naphthalen-2-yl) carbonochloridothioate;o-naphthalen-2-yl carbonochloridothioate;2-naphthyl chlorothioformate;T6L7YU9JEP;C11-H7-Cl-O-S;O-2-Naphthylchloro thioformate;SCHEMBL1403191;DTXSID20146934;AKOS017345193;o-naphthalen-2-ylcarbonochloridothioate;Chlorothioformic acid O-(2-naphthyl) ester;CS-0235283;FT-0697238;EN300-154917;Carbonochloridothioic acid, O-2-naphthalenyl ester;SR-01000945083;SR-01000945083-1;W-108796

Chemical Property of O-2-Naphthyl chlorothioformate

Chemical Property:

• Vapor Pressure: 0.000243mmHg at 25°C
• Melting Point: 76-77 °C
• Refractive Index: 1.693
• Boiling Point: 334.761 °C at 760 mmHg
• Flash Point: 156.258 °C
• PSA: 41.32000
• Density: 1.358 g/cm³
• LogP: 3.74230
• XLogP3: 4.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 221.9906137
• Heavy Atom Count: 14
• Complexity: 219

Purity/Quality:

99.9% ^*data from raw suppliers

Naphthalen-2-ylChloromethanethioate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C=C(C=CC2=C1)OC(=S)Cl

Technology Process of O-2-Naphthyl chlorothioformate

There total 3 articles about O-2-Naphthyl chlorothioformate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

thiophosgene (463-71-8) + sodium 2-naphtholate (875-83-2) → O-2-naphthalenyl-carbonochloridothioate (10506-37-3)

Guidance literature:

With chloroform;

Reference yield:

thiophosgene (463-71-8) + β-naphthol (135-19-3) → O-2-naphthalenyl-carbonochloridothioate (10506-37-3)

Guidance literature:

With sodium hydroxide; In dichloromethane; water; for 1h;

DOI:10.1021/jo102467j

Reference yield:

→ O-2-naphthalenyl-carbonochloridothioate (10506-37-3)

Guidance literature:

nach Rivier;

upstream raw materials:

thiophosgene

sodium 2-naphtholate

β-naphthol

Downstream raw materials:

O-(naphthalen-2-yl) N,N-dimethylcarbamothioate

β-naphthyl N-cyclohexyl-N-methylthiocarbamate

O-(2-naphthyl) N-methyl-N-phenyl thiocarbamate

N-methyl-N-phenyl-2-naphthylamide

Refernces

• 1、 Baroudi, Abdulkader,Alicea, Jeremiah,Flack, Phillip,Kirincich, Jason,Alabugin, Igor V.. "Radical OfC transposition: A metal-free process for conversion of phenols into benzoates and benzamides". experimental part. p. 1521 - 1537. Retrieved 2011/06/11.