2,4-Cyclohexadien-1-one, 6-imino-

Base Information

• Chemical Name: 2,4-Cyclohexadien-1-one, 6-imino-
• CAS No.: 4377-76-8
• Molecular Formula: C6H5NO
• Molecular Weight: 107.112
• Mol file: 4377-76-8.mol

Synonyms:o-quinoneimine;2,4-Cyclohexadien-1-one,6-imino;o-quinonimine;6-Iminocyclohexa-2,4-dienone;ortho-benzoquinone monoimine;6-Imino-2,4-cyclohexadien-1-one;o-benzoquinoneimine;iminocyclohexadienone;1,2-Benzoquinone monoimine;

Chemical Property of 2,4-Cyclohexadien-1-one, 6-imino-

Chemical Property:

• PSA: 40.92000
• LogP: 0.80100

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4-Cyclohexadien-1-one, 6-imino-

There total 4 articles about 2,4-Cyclohexadien-1-one, 6-imino- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

2-amino-phenol (95-55-6) → 6-Imino-2,4-cyclohexadien-1-one (4377-76-8)

Guidance literature:

With air atmosphere; benzodipteridine; In N,N-dimethyl acetamide; for 24h; Rate constant; Mechanism; Ambient temperature; 0.1M phosphate buffer pH 6.6; pH rate profil;

Reference yield:

2-azidophenol (24541-44-4) → 6-Imino-2,4-cyclohexadien-1-one (4377-76-8)

Guidance literature:

at -263.2 ℃; Irradiation;

DOI:10.1002/jlac.199619961206

Reference yield:

mer-[CuII(2,2′-azobispyridine)3][PF6]2 + 2-amino-phenol (95-55-6) → 6-Imino-2,4-cyclohexadien-1-one (4377-76-8) + [CuI(2,2′-azobispyridine)2][PF6]

Guidance literature:

In dichloromethane; at 24.84 ℃;

DOI:10.1021/ic502750u

upstream raw materials:

2-amino-phenol

2-azidophenol

Downstream raw materials:

2-aminophenoxazin-3-one

Refernces

• 1、 Maity, Suvendu,Kundu, Suman,Weyhermüller, Thomas,Ghosh, Prasanta. "Tris(2,2′-azobispyridine) complexes of copper(II): X-ray structures, reactivities, and the radical nonradical bis(ligand) analogues". . p. 1300 - 1313. Retrieved 2015/06/11.
• 2、 Nazarov,Khursan,Chainikova,Komissarov. "Effect of the structure of amines on the rate constants of their reactions with diphenylcarbonyl oxide". . p. 190 - 194. Retrieved 2007/10/03.