Dimethyl(4-vinylphenyl)silane

Base Information

• Chemical Name: Dimethyl(4-vinylphenyl)silane
• CAS No.: 4556-72-3
• Molecular Formula: C10H14Si
• Molecular Weight: 162.307
• DSSTox Substance ID: DTXSID20785327
• Mol file: 4556-72-3.mol

Synonyms:Dimethyl(4-vinylphenyl)silane;4556-72-3;(4-Ethenylphenyl)(dimethyl)silane;(4 - vinyl phenyl) dimethyl silane;(4-ethenylphenyl)-dimethylsilane;p-dimethylsilylstyrene;p-vinylphenyl dimethylsilane;DTXSID20785327;MFCD28975321;BS-17076;CS-0452718;A872362

Chemical Property of Dimethyl(4-vinylphenyl)silane

Chemical Property:

• PSA: 0.00000
• LogP: 2.02330
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 161.078651949
• Heavy Atom Count: 11
• Complexity: 121

Purity/Quality:

99%, ^*data from raw suppliers

Dimethyl(4-vinylphenyl)silane 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)C1=CC=C(C=C1)C=C

Technology Process of Dimethyl(4-vinylphenyl)silane

There total 3 articles about Dimethyl(4-vinylphenyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

dimethylmonochlorosilane (1066-35-9) + 1-bromo-4-ethenyl-benzene (2039-82-9) → dimethyl(4-vinylphenyl)silane (4556-72-3)

Guidance literature:

1-bromo-4-ethenyl-benzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 2.5h;

dimethylmonochlorosilane; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 8h;

Reference yield:

4-vinylbenzyl chloride (1073-67-2,24991-47-7) + dimethylmonochlorosilane (1066-35-9) → dimethyl(4-vinylphenyl)silane (4556-72-3)

Guidance literature:

4-vinylbenzyl chloride; With magnesium;

dimethylmonochlorosilane;

DOI:10.1016/j.cclet.2012.10.018

Reference yield:

→ dimethyl(4-vinylphenyl)silane (4556-72-3)

Guidance literature:

entspr.Chlorsilan, LiAlH4;

DOI:10.1002/macp.1964.020770102

upstream raw materials:

4-vinylbenzyl chloride

dimethylmonochlorosilane

1-bromo-4-ethenyl-benzene

Downstream raw materials:

tert-butyl 4-vinylphenylcarbamate

Refernces

• 1、 Wang, Bai,Ma, Hong Wei,Wang, Yan Shai,Li, Yang. "Synthesis and characterization of novel liquid crystalline polystyrene". . p. 915 - 917. Retrieved 2013.
• 2、 -. "Heme Protein Catalysts for Carbon-Silicon Bond Formation In Vitro and In Vivo". Paragraph 0270; 0271. . Retrieved 2017/08/26.