2,4-BIS(CHLOROMETHYL)MESITYLENE

Base Information

• Chemical Name: 2,4-BIS(CHLOROMETHYL)MESITYLENE
• CAS No.: 1585-17-7
• Molecular Formula: C11H14 Cl2
• Molecular Weight: 217.138
• Hs Code.: 2903999090
• Mol file: 1585-17-7.mol

Synonyms:1,3,5-Trimethyl-2,4-bis(chloromethyl)benzene;1,3-Bis(chloromethyl)-2,4,6-trimethylbenzene; 2,4,6-Trimethyl-m-xylylenedichloride; 2,4-Bis(chloromethyl)-1,3,5-trimethylbenzene;2,4-Bis(chloromethyl)mesitylene; 2,6-Bis(chloromethyl)-1,3,5-trimethylbenzene;Bis(chloromethyl)mesitylene; NSC 1241

Chemical Property of 2,4-BIS(CHLOROMETHYL)MESITYLENE

Chemical Property:

• Vapor Pressure: 0.00102mmHg at 25°C
• Melting Point: 105-107 °C(lit.)
• Refractive Index: 1.5620 (estimate)
• Boiling Point: 180 °C20 mm Hg(lit.)
• Flash Point: 154.9°C
• PSA: 0.00000
• Density: 1.121g/cm³
• LogP: 4.08940

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,4-Bis(chloromethyl)-1,3,5-trimethylbenzene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 34
• Safety Statements: 23-26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 2,4-BIS(CHLOROMETHYL)MESITYLENE

There total 7 articles about 2,4-BIS(CHLOROMETHYL)MESITYLENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

chloromethyl methyl ether (107-30-2) + 1,3,5-trimethyl-benzene (108-67-8) → 2,4-bis(chloromethyl)mesitylene (1585-17-7)

Guidance literature:

With zinc(II) chloride; at 20 ℃; for 0.166667h;

DOI:10.3184/030823409X465222

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 1,3,5-trimethyl-benzene (108-67-8) → 2,4-bis(chloromethyl)mesitylene (1585-17-7) + 2-chloromethyl-1,3,5-trimethylbenzene (1585-16-6)

Guidance literature:

With hydrogenchloride; at 65 ℃; Einleiten von HCl;

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 1,3,5-trimethyl-benzene (108-67-8) → 2,4,6-tris(chloromethyl)-mesitylene (3849-01-2) + 2,4-bis(chloromethyl)mesitylene (1585-17-7) + 2-chloromethyl-1,3,5-trimethylbenzene (1585-16-6)

Guidance literature:

With hydrogenchloride; for 2h; Title compound not separated from byproducts.; Heating;

DOI:10.1134/S1070363207040196

upstream raw materials:

chloromethyl methyl ether

acetic acid

1,3,5-trimethyl-benzene

formaldehyd

Downstream raw materials:

(3-{[Bis-(2-pyridin-2-yl-ethyl)-amino]-methyl}-2,4,6-trimethyl-benzyl)-bis-(2-pyridin-2-yl-ethyl)-amine

(2,4,6-trimethyl-1,3-phenylene)bis(methylene)dicarbamimidothioate

1,3-bis(1-imidazol-1-ylmethyl)-2,4,6-trimethylbenzene

3-amino-2,4,6-trimethylphenylacetonitrile

Refernces

• 1、 Zenkevich,Makarov. "Identification of alkylarene chloromethylation products using gas-chromatographic retention indices". . p. 611 - 619. Retrieved 2008/03/18.