4'-Methoxy-4-dimethylaminoazobenzene

Base Information

• Chemical Name: 4'-Methoxy-4-dimethylaminoazobenzene
• CAS No.: 3009-50-5
• Molecular Formula: C15H17 N3 O
• Molecular Weight: 255.319
• Hs Code.: 2927000090
• DSSTox Substance ID: DTXSID601031199,DTXSID001043643
• Nikkaji Number: J33.824I
• Mol file: 3009-50-5.mol

Synonyms:4'-Methoxy-4-dimethylaminoazobenzene;3009-50-5;BRN 0749612;4-[(4-methoxyphenyl)diazenyl]-N,N-dimethylaniline;N,N-Dimethyl-p-(4-methoxyphenylazo)aniline;CCRIS 8706;ANILINE, N,N-DIMETHYL-p-(4-METHOXYPHENYLAZO)-;4-(Dimethylamino)-4'-methoxyazobenzene;4-16-00-00497 (Beilstein Handbook Reference);SCHEMBL5981957;DTXSID001043643;DTXSID601031199;LS-19752;Aniline, p-[(p-methoxyphenyl)azo]-N,N-dimethyl-;Benzenamine, 4-[(4-methoxyphenyl)azo]-N,N-dimethyl-;4-[(4-METHOXYPHENYL)AZO]-N,N-DIMETHYLBENZENAMINE;4-[(E)-(4-methoxyphenyl)diazenyl]-N,N-dimethylaniline;118527-20-1

Chemical Property of 4'-Methoxy-4-dimethylaminoazobenzene

Chemical Property:

• Vapor Pressure: 6.06E-07mmHg at 25°C
• Refractive Index: 1.5600 (estimate)
• Boiling Point: 410.4°Cat760mmHg
• Flash Point: 202°C
• PSA: 37.19000
• Density: 1.05g/cm³
• LogP: 4.17660
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 255.137162174
• Heavy Atom Count: 19
• Complexity: 277

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)C1=CC=C(C=C1)N=NC2=CC=C(C=C2)OC

Technology Process of 4'-Methoxy-4-dimethylaminoazobenzene

There total 6 articles about 4'-Methoxy-4-dimethylaminoazobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

4-methoxybenzenediazonium tetrafluoroborate (459-64-3) + N,N-dimethyl-aniline (121-69-7,77733-26-7) → 4-(4-methoxyphenylazo)-N,N-dimethylaniline (3009-50-5)

Guidance literature:

With 2,4,6-Trinitrophenol; In chloroform; water; at 0 - 5 ℃; for 0.7h;

DOI:10.1246/bcsj.61.905

Reference yield: 49.0%

C15H17N3O3 (108193-69-7) → [4-(4-Methoxy-phenyl-ONN-azoxy)-phenyl]-dimethyl-amine (99686-17-6) + 4-(4-methoxyphenylazo)-N,N-dimethylaniline (3009-50-5)

Guidance literature:

In benzene; at 17 ℃; for 6h; Irradiation;

Reference yield: 32.0%

4-(4-methoxyphenylazo)-N,N-dimethylaniline N-oxide (108178-66-1) → 4'-methoxy-1-N-methylaminoazobenzene (21924-71-0) + N-[4-(4-Methoxy-phenylazo)-phenyl]-N-methyl-formamide (99686-19-8) + 4-(4-methoxyphenylazo)-N,N-dimethylaniline (3009-50-5)

Guidance literature:

In benzene; at 17 ℃; for 6h; Irradiation;

upstream raw materials:

4-methoxy-aniline

4-methoxybenzenediazonium tetrafluoroborate

N,N-dimethyl-aniline

4-amino-N,N-dimethylaniline

Downstream raw materials:

C₁₅H₁₇N₃O₃

4-(4-methoxyphenylazo)-N,N-dimethylaniline N-oxide

Refernces

• 1、 Hashida, Yoji,Kubota, Kazuhiro,Sekiguchi, Shizen. "Phase-Transfer-Catalyzed Azo Coupling Reactions in Two-Phase Systems". . p. 905 - 910. Retrieved 2007/10/02.
• 2、 Albini, Angelo,Fasani, Elisa,Moroni, Micaela,Pietra, Silvio. "Photochemical Decomposition of 4-Arylazo- and 4-Arylazoxy-N,N-dialkylaniline N-Oxides". . p. 1439 - 1444. Retrieved 2007/10/02.