Methyl propyl sulfoxide

Base Information

• Chemical Name: Methyl propyl sulfoxide
• CAS No.: 14094-08-7
• Molecular Formula: C4H10 O S
• Molecular Weight: 106.189
• DSSTox Substance ID: DTXSID40930958
• Nikkaji Number: J512.262G
• Mol file: 14094-08-7.mol

Synonyms:Methyl propyl sulfoxide;Propane, 1-(methylsulfinyl)-;14094-08-7;1-METHANESULFINYLPROPANE;1-methylsulfinylpropane;1-(Methylsulfinyl)propane;1-(Methanesulfinyl)propane;SCHEMBL40833;1-(Methylsulfinyl)propane #;DTXSID40930958;WOBARLJSXVAEGX-UHFFFAOYSA-N

Chemical Property of Methyl propyl sulfoxide

Chemical Property:

• Vapor Pressure: 0.258mmHg at 25°C
• Boiling Point: 212°Cat760mmHg
• Flash Point: 82°C
• Density: 1.02g/cm³
• XLogP3: 0.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 106.04523611
• Heavy Atom Count: 6
• Complexity: 51.5

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCS(=O)C

Technology Process of Methyl propyl sulfoxide

There total 4 articles about Methyl propyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1-(methylthio)-propane (3877-15-4) → methyl n-propyl sulfoxide (14094-08-7)

Guidance literature:

With C₁₉H₁₁F₂N₃O₃V; dihydrogen peroxide; In acetic acid; at 25 ℃; for 0.116667h;

DOI:10.1007/s13738-018-1480-2

Reference yield:

1-(methylthio)-propane (3877-15-4) → methyl n-propyl sulfoxide (14094-08-7) + (methylsulfonyl)propane (1977-37-3)

Guidance literature:

With sodium peroxoniobate; dihydrogen peroxide; cetyltrimethylammonim bromide; In dichloromethane; at 25 ℃; for 2.5h;

Reference yield:

allylmethylsulfoxide (21892-75-1) → methyl n-propyl sulfoxide (14094-08-7)

Guidance literature:

With C₆H₁₆P₂Rh⁽¹⁺⁾; hydrogen;

DOI:10.1021/ja409824b

upstream raw materials:

1-(methylthio)-propane

allylmethylsulfoxide

Refernces

• 1、 Mikolajczyk,Para. "". . p. 1192. Retrieved 1969.
• 2、 Zabardasti, Abedien,Shangaie, Sayed Asad. "Vanadium (IV) complexes with Schiff base ligands derived from 2,3-diaminopyridine as catalyst for the oxidation of sulfides to sulfoxides with H2O2". . p. 57 - 64. Retrieved 2019/01/14.
• 3、 Dornan, Peter K.,Kou, Kevin G. M.,Houk,Dong, Vy M.. "Dynamic kinetic resolution of allylic sulfoxides by Rh-catalyzed hydrogenation: A combined theoretical and experimental mechanistic study". . p. 291 - 298. Retrieved 2014/01/23.