N-(Naphthalen-2-yl)naphthalen-1-amine

Base Information

• Chemical Name: N-(Naphthalen-2-yl)naphthalen-1-amine
• CAS No.: 4669-06-1
• Molecular Formula: C20H15N
• Molecular Weight: 269.346
• Hs Code.: 2921450090
• European Community (EC) Number: 680-146-5
• NSC Number: 85190
• DSSTox Substance ID: DTXSID50292736
• Nikkaji Number: J370.641I
• Wikidata: Q72472403
• Mol file: 4669-06-1.mol

Synonyms:1,2'-Dinaphthylamine;4669-06-1;N-(Naphthalen-2-yl)naphthalen-1-amine;1,2-Dinaphthylamine;N-naphthalen-1-ylnaphthalen-2-amine;N-(2-Naphthyl)-1-naphthylamine;1,2'-Dinaphthylamine (purified by sublimation);N-2-Naphthyl-1-naphthylamine;NSC85190;1,2'-Iminodinaphthalene;NCIOpen2_004854;SCHEMBL557025;1-Naphthylamine, N-2-naphthyl-;DTXSID50292736;UNJZLNFHHINVOB-UHFFFAOYSA-N;MFCD01632468;NSC-85190;1-Naphthalenamine, N-2-naphthalenyl-;AKOS015951435;N-(2-Naphthyl)-1-naphthylamine, 95%;AS-30145;D2988;FT-0753496

Chemical Property of N-(Naphthalen-2-yl)naphthalen-1-amine

Chemical Property:

• Melting Point: 110 °C
• Boiling Point: 457 °C at 760 mmHg
• Flash Point: 250.5 °C
• PSA: 12.03000
• Density: 1.203 g/cm³
• LogP: 5.80960
• Storage Temp.: 2-8°C(protect from light)
• XLogP3: 6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 269.120449483
• Heavy Atom Count: 21
• Complexity: 339

Purity/Quality:

98%,99%, ^*data from raw suppliers

N-naphthalen-1-ylnaphthalen-2-amine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 22-41
• Safety Statements: 36-39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C=C(C=CC2=C1)NC3=CC=CC4=CC=CC=C43

Technology Process of N-(Naphthalen-2-yl)naphthalen-1-amine

There total 7 articles about N-(Naphthalen-2-yl)naphthalen-1-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

tri(naphthalen-2-yl) phosphate (7657-86-5) + 1-amino-naphthalene (134-32-7) → N-naphthyl-N-2-naphthylamine (4669-06-1)

Guidance literature:

With NiCl(1-naphthyl)(PPh₃)2; sodium hydride; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride; In 1,4-dioxane; at 110 ℃; Inert atmosphere;

DOI:10.1021/ol201437g

Reference yield: 78.3%

→ N-naphthyl-N-2-naphthylamine (4669-06-1)

Guidance literature:

With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; In cyclohexane; toluene; for 2h; Inert atmosphere; Reflux;

Reference yield: 58.0%

naphthalen-2-yl N,N-dimethylsulfamic acid (1145-08-0) + 1-Naphthylamino-magnesiumbromid → N-naphthyl-N-2-naphthylamine (4669-06-1)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene; In tetrahydrofuran; 1,4-dioxane; at 150 ℃; for 24h; Inert atmosphere;

DOI:10.1016/j.tetlet.2012.08.015

upstream raw materials:

1-naphthylamine hydrochloride

1-amino-naphthalene

β-naphthol

2-naphthylamine hydrochloride

Downstream raw materials:

dibenz[a,h]acridine

4,4'-bis[N-(1-naphthyl)-N-(2-naphthyl)amino]biphenyl

N-(4-bromophenyl)-N-(naphtho-2-yl)-1-naphthylamine

naphthalene-2-yl-naphthalene-1-yl-{6-[4-(naphthalene-2-yl-phenyl-amino)-phenyl]-pyrene-1-yl}-amine

Refernces

• 1、 -. "COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND A ELECTRONIC DEVICE THEREOF". Paragraph 0103; 0106-0109. . Retrieved 2021/06/22.
• 2、 -. "COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND A ELECTRONIC DEVICE THEREOF". Paragraph 0123; 0127-0131. . Retrieved 2020/06/24.