Tetrapentylammonium bromide

Base Information

• Chemical Name: Tetrapentylammonium bromide
• CAS No.: 866-97-7
• Molecular Formula: C20H44 N . Br
• Molecular Weight: 378.48
• Hs Code.: 29239000
• European Community (EC) Number: 212-756-0
• DSSTox Substance ID: DTXSID40883596
• Mol file: 866-97-7.mol

Synonyms:tetrapentylammonium;tetrapentylammonium bromide;tetrapentylammonium chloride;tetrapentylammonium hydrogen sulfate;tetrapentylammonium hydroxide;tetrapentylammonium iodide;tetrapentylammonium ion;tetrapentylammonium metaphosphate (3:1);tetrapentylammonium metaphosphate (4:1);tetrapentylammonium monopicrate;tetrapentylammonium nitrate;tetrapentylammonium perchlorate

Chemical Property of Tetrapentylammonium bromide

Chemical Property:

• Melting Point: 100-101 °C(lit.)
• Refractive Index: 1.5260 (estimate)
• PSA: 0.00000
• Density: 0.92333 g/cm3 (35.00℃)
• LogP: 3.56800
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: Soluble in water
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 16
• Exact Mass: 377.26571
• Heavy Atom Count: 22
• Complexity: 155

Purity/Quality:

98% ^*data from raw suppliers

Tetrapentylammonium bromide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Nitrogen Compounds -> Quaternary Amines
• Canonical SMILES: CCCCC[N+](CCCCC)(CCCCC)CCCCC.[Br-]
• Uses: Tetrapentylammonium bromide can be used:As a versatile structure-directing agent for the synthesis of Zeolite-like heterobimetallic cyanide frameworks.As an alkylating agent for rhodium(I)-catalyzed alkylation reaction of benzylic amines and for N-alkylation of azaheterocycles.As a precursor to prepare a Cobalt-complex, {[(Pentyl)4N]3CoBr3}Cl2, which is used as a catalyst in the synthesis of multiwalled carbon nanotubes (MWCNTs).Electrochemical synthesis of stable graphite intercalation compounds (GICs) containing tetrapentylammonium cations has been reported.

Technology Process of Tetrapentylammonium bromide

There total 3 articles about Tetrapentylammonium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Bromopentane (110-53-2) + tripentylamine (621-77-2) → tetrapentylammonium bromide (866-97-7)

Guidance literature:

In ethanol;

DOI:10.1002/jps.2600550413

Reference yield:

tetrapentylammonium iodide (2498-20-6) → tetrapentylammonium bromide (866-97-7)

Guidance literature:

With ammonium bromide; In dichloromethane; water;

DOI:10.1021/acs.cgd.5b01342

Reference yield:

→ tetrapentylammonium bromide (866-97-7)

Guidance literature:

DOI:10.1039/c29710001160

upstream raw materials:

1-Bromopentane

tripentylamine

tetrapentylammonium iodide

Downstream raw materials:

propyl bromide

Methanesulfonatetetrapentyl-ammonium;

tetrapentylammonium hydroxide

[(C₅H₁₁)4N]⁽¹⁺⁾*[(C₆H₅)3SnOCOCF₃(Br)]^(1-) = [(C₅H₁₁)4N][(C₆H₅)3SnOCOCF₃(Br)]

Refernces

• 1、 Gordon,J.E.,SubbaRao,G.N.. "-". . p. 7445 - 7454. Retrieved 1978.
• 2、 Kellett Jr.,Doggett. "Cholinergic anionic receptors. 3. Steric requirements for quaternary ammonium inhibitors of acetylcholinesterase II.". . p. 414 - 417. Retrieved 2007/10/05.