2-methyl-N-[2-(2-oxoimidazolidin-1-yl)ethyl]prop-2-enamide

Base Information

• Chemical Name: 2-methyl-N-[2-(2-oxoimidazolidin-1-yl)ethyl]prop-2-enamide
• CAS No.: 3089-19-8
• Deprecated CAS: 1338-22-3
• Molecular Formula: C9H15 N3 O2
• Molecular Weight: 197.237
• Hs Code.: 2933990090
• European Community (EC) Number: 221-426-5
• UNII: 0LIZ3767RG
• DSSTox Substance ID: DTXSID0044652
• Nikkaji Number: J217.259C
• Wikidata: Q27236947
• Mol file: 3089-19-8.mol

Synonyms:3089-19-8;2-methyl-N-[2-(2-oxoimidazolidin-1-yl)ethyl]prop-2-enamide;N-(2-Methacrylamidoethyl)ethylene urea;EINECS 221-426-5;UNII-0LIZ3767RG;0LIZ3767RG;2-Propenamide, 2-methyl-N-(2-(2-oxo-1-imidazolidinyl)ethyl)-;N-(2-(2-Oxoimidazolidin-1-yl)ethyl)methacrylamide;N-[2-(2-Oxo-1-imidazolidinyl)ethyl]methacrylamide;N-[2-(2-Oxoimidazolidin-1-yl)ethyl]methacrylamide;2-Methyl-N-[2-(2-oxo-1-imidazolidinyl)ethyl]-2-propenamide;2-Propenamide, 2-methyl-N-[2-(2-oxo-1-imidazolidinyl)ethyl]-;N-(2-(2-OXO-1-IMIDAZOLIDINYL)ETHYL)-METH ACRYLAMIDE, TECH.;N-(2-(2-OXO-1-IMIDAZOLIDINYL)ETHYL)METHACRYLAMIDE;2-METHYL-N-(2-(2-OXOIMIDAZOLIDIN-1-YL)ETHYL)PROP-2-ENAMIDE;MAEEU;SCHEMBL166209;DTXSID0044652;AKOS006227846;W-109860;1-(2-METHACRYLOYLAMINOETHYL)-2-IMIDAZOLIDINONE;N-(2-(METHACRYLOYLAMINO)ETHYL)IMIDAZOLIDINONE;Q27236947;ACRYLAMIDE, 2-METHYL-N-(2-(2-OXO-1-IMIDAZOLIDINYL)ETHYL)-

Chemical Property of 2-methyl-N-[2-(2-oxoimidazolidin-1-yl)ethyl]prop-2-enamide

Chemical Property:

• Vapor Pressure: 9.86E-11mmHg at 25°C
• Melting Point: 114.5-117.0 °C
• Refractive Index: n20/D 1.456(lit.)
• Boiling Point: 515.4°Cat760mmHg
• PKA: 14.39±0.20(Predicted)
• Flash Point: 265.5°C
• PSA: 61.44000
• Density: 1.115g/cm³
• LogP: 0.36150
• XLogP3: -0.4
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 197.116426730
• Heavy Atom Count: 14
• Complexity: 263

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 45-37/38-41-43
• Safety Statements: 53-23-26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=C)C(=O)NCCN1CCNC1=O

Technology Process of 2-methyl-N-[2-(2-oxoimidazolidin-1-yl)ethyl]prop-2-enamide

There total 2 articles about 2-methyl-N-[2-(2-oxoimidazolidin-1-yl)ethyl]prop-2-enamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.9%

2-hydroxyethylethyleneurea (161663-36-1) + methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → 2-methyl-3-[2-(2-oxo-imidazolidin-1-yl)-ethoxy]-propionic acid + 2-methyl-3-[3-[2-(methacryloylamino)ethyl]-2-oxo-imidazolidin-1-yl]-propionic acid + N-[2-[3-methacryloyl-2-oxo-imidazolidin-1-yl]-ethyl]-methacrylamide + N-[2-(2-oxo-imidazolidin-1-yl)-ethyl]-methacrylamide (3089-19-8) + 2-(2-oxoimidazolidinyl)ethyl 2-methylprop-2-enoate (86261-90-7)

Guidance literature:

With 5A molecular sieve; Novozym 435 (immobilized lipase from Candida antarctica B); at 40 ℃; for 72h; Product distribution / selectivity;

Reference yield:

2-aminoethylimidazolidone (6281-42-1) + Methacryloyl chloride (920-46-7,26937-45-1) → N-[2-(2-oxo-imidazolidin-1-yl)-ethyl]-methacrylamide (3089-19-8)

Guidance literature:

With chloroform;

upstream raw materials:

2-aminoethylimidazolidone

Methacryloyl chloride

2-hydroxyethylethyleneurea

methacrylic acid methyl ester

Refernces