diallyl sulfone

Base Information

• Chemical Name: diallyl sulfone
• CAS No.: 16841-48-8
• Molecular Formula: C6H10 O2 S
• Molecular Weight: 146.21
• Hs Code.: 2904100000
• Mol file: 16841-48-8.mol

Synonyms:1-Propene,3,3'-sulfonylbis- (9CI); Allyl sulfone (6CI,7CI,8CI); Bis(allyl) sulfone;Diallyl sulfone; NSC 10979

Chemical Property of diallyl sulfone

Chemical Property:

• Vapor Pressure: 0.0192mmHg at 25°C
• Refractive Index: 1.4893 (estimate)
• Boiling Point: 261°Cat760mmHg
• Flash Point: 125°C
• PSA: 42.52000
• Density: 1.053g/cm³
• LogP: 1.85400

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of diallyl sulfone

There total 2 articles about diallyl sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-tolyl iodide (624-31-7) + allyltrimethoxysilane (2551-83-9) → diallyl sulfone (16841-48-8) + 1-methyl-4-(prop-2-ene-1-sulfonyl)benzene (3112-87-6)

Guidance literature:

4-tolyl iodide; allyltrimethoxysilane; With palladium(II) acetylacetonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; tetrabutylammonium triphenyldifluorosilicate; In tetrahydrofuran; Glovebox;

With potassium pyrosulfite; at 600 ℃; Glovebox; Inert atmosphere;

In tetrahydrofuran; at 20 - 80 ℃; for 4h; regioselective reaction; Glovebox;

DOI:10.1039/c9cc06858a

Reference yield:

4-tolyl iodide (624-31-7) + allyl(methoxy)dimethylsilane (30535-30-9) → diallyl sulfone (16841-48-8) + 1-methyl-4-(prop-2-ene-1-sulfonyl)benzene (3112-87-6)

Guidance literature:

4-tolyl iodide; allyl(methoxy)dimethylsilane; With palladium(II) acetylacetonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; tetrabutylammonium triphenyldifluorosilicate; In tetrahydrofuran; Glovebox;

With potassium pyrosulfite; at 600 ℃; Glovebox; Inert atmosphere;

In tetrahydrofuran; at 20 - 80 ℃; for 4h; regioselective reaction; Glovebox;

DOI:10.1039/c9cc06858a

Reference yield: 98.0%

diallyl sulfone (16841-48-8) → 3-Sulfolene (77-79-2)

Guidance literature:

With C₃₄H₄₃Cl₂N₃O₂Ru; In dichloromethane; at 35 ℃; for 0.5h; Inert atmosphere;

DOI:10.1016/j.poly.2014.03.034

upstream raw materials:

4-tolyl iodide

allyltrimethoxysilane

allyl(methoxy)dimethylsilane

Downstream raw materials:

propyl sulfone

2,6-dimethyl-[1,4]oxathiane-4,4-dioxide

1-<2-(4-Hydroxyphenyl)ethyl>-2,6-dimethyl-4,1-thiazane 4,4-dioxide

2-iodo-1,3-bis(p-tolylsulphonyl)propane

Refernces