2,2'-[[3-Acetamido-4-[(4-nitrophenyl)azo]phenyl]imino]diethyl diacetate

Base Information

• Chemical Name: 2,2'-[[3-Acetamido-4-[(4-nitrophenyl)azo]phenyl]imino]diethyl diacetate
• CAS No.: 1533-74-0
• Molecular Formula: C22H25N5O7
• Molecular Weight: 471.47
• Hs Code.: 3204110000
• European Community (EC) Number: 216-247-4
• DSSTox Substance ID: DTXSID101024616
• Nikkaji Number: J206.754D
• Mol file: 1533-74-0.mol

Synonyms:1533-74-0;2-[3-acetamido-N-(2-acetyloxyethyl)-4-[(4-nitrophenyl)diazenyl]anilino]ethyl acetate;EINECS 216-247-4;2,2'-[[3-ACETAMIDO-4-[(4-NITROPHENYL)AZO]PHENYL]IMINO]DIETHYL DIACETATE;Acetamide,N-[5-[bis[2-(acetyloxy)ethyl]amino]-2-[2-(4-nitrophenyl)diazenyl]phenyl]-;2,2'-3-Acetamido-4-(4-nitrophenyl)azophenyliminodiethyl diacetate;2,2'-((3-Acetamido-4-((4-nitrophenyl)azo)phenyl)imino)diethyl diacetate;2,2/'-[[3-acetamido-4-[(4-nitrophenyl)azo]phenyl]imino]diethyl diacetate;Acetamide, N-(5-(bis(2-(acetyloxy)ethyl)amino)-2-((4-nitrophenyl)azo)phenyl)-;Acetamide, N-[5-[bis[2-(acetyloxy)ethyl]amino]-2-[(4-nitrophenyl)azo]phenyl]-;DTXSID101024616;W-109676;N-[5-[Bis[2-(acetyloxy)ethyl]amino]-2-[(4-nitrophenyl)azo]phenyl]acetamide

Chemical Property of 2,2'-[[3-Acetamido-4-[(4-nitrophenyl)azo]phenyl]imino]diethyl diacetate

Chemical Property:

• Melting Point: 120 °C
• Boiling Point: 686.4 °C at 760 mmHg
• PKA: 14.23±0.70(Predicted)
• Flash Point: 368.9°C
• PSA: 155.48000
• Density: 1.3 g/cm³
• LogP: 4.49740
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 12
• Exact Mass: 471.17539815
• Heavy Atom Count: 34
• Complexity: 714

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)NC1=C(C=CC(=C1)N(CCOC(=O)C)CCOC(=O)C)N=NC2=CC=C(C=C2)[N+](=O)[O-]

Technology Process of 2,2'-[[3-Acetamido-4-[(4-nitrophenyl)azo]phenyl]imino]diethyl diacetate

There total 3 articles about 2,2'-[[3-Acetamido-4-[(4-nitrophenyl)azo]phenyl]imino]diethyl diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-nitro-aniline (100-01-6,104810-17-5) + 3-(N,N-di(acetyloxyethyl)amino)-N-phenylacetamide (27059-08-1) → 2,2'-({3-acetamido-4-[(4-nitrophenyl)azo]phenyl}imino)diethyl diacetate (1533-74-0)

Guidance literature:

4-nitro-aniline; 3-(N,N-di(acetyloxyethyl)amino)-N-phenylacetamide; With 1-ethenyl-2-pyrrolidinone; nitrosylsulfuric acid; sulfuric acid; at 0 - 5 ℃; for 2h; Inert atmosphere; Large scale;

With ammonia; at 65 - 70 ℃; for 1h; pH=6 - 7; pH-value; Reagent/catalyst; Temperature; Large scale;

Reference yield:

N,N-diacetoxyethyl-m-aminoacetanilide + 4-nitro-aniline (100-01-6,104810-17-5) → 2,2'-({3-acetamido-4-[(4-nitrophenyl)azo]phenyl}imino)diethyl diacetate (1533-74-0)

Guidance literature:

N,N-diacetoxyethyl-m-aminoacetanilide; 4-nitro-aniline; With sulfuric acid; sodium nitrite; In water;

With aminosulfonic acid; In water; at 10 - 35 ℃; for 1h;

Reference yield:

→ 2,2'-({3-acetamido-4-[(4-nitrophenyl)azo]phenyl}imino)diethyl diacetate (1533-74-0)

Guidance literature:

entspr. Di-(β-Hydroxyethyl)amino-Verb. mit Ac2O/Erhitzen;

upstream raw materials:

4-nitro-aniline

3-(N,N-di(acetyloxyethyl)amino)-N-phenylacetamide

Refernces

• 1、 -. "Disperse dye composition, and preparation method and application thereof". Paragraph 0107-0110. . Retrieved 2017/08/28.