METHYL 11-BROMOUNDECANOATE

Base Information

• Chemical Name: METHYL 11-BROMOUNDECANOATE
• CAS No.: 6287-90-7
• Molecular Formula: C12H23BrO2
• Molecular Weight: 279.217
• Hs Code.: 2915900090
• Mol file: 6287-90-7.mol

Synonyms:11-Bromoundecanoic acid methyl ester;

Chemical Property of METHYL 11-BROMOUNDECANOATE

Chemical Property:

• Vapor Pressure: 0.000805mmHg at 25°C
• Melting Point: 17℃
• Refractive Index: n20/D 1.465(lit.)
• Boiling Point: 305.8 °C at 760 mmHg
• Flash Point: 160.3 °C
• PSA: 26.30000
• Density: 1.147 g/cm³
• LogP: 4.06520
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility.: Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)

Purity/Quality:

98%,99%, ^*data from raw suppliers

Methyl 11-Bromoundecanoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Methyl 11-bromoundecanoate can be used as a reactant to synthesize: Methyl 11-(2,5-dibromophenoxy)undecanoate, which is employed as a precursor to prepare acetylenic cyclophanes. Methyl 11-[(1-phenyl-1H-tetrazol-5-yl)thio]undecanoate, a key intermediate applicable in the synthesis of emmyguyacins side chain.Betain derivatives of 11-bromoundecanoic acid, as potential microbial agents.

Technology Process of METHYL 11-BROMOUNDECANOATE

There total 13 articles about METHYL 11-BROMOUNDECANOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diazomethane (186581-53-3,908094-01-9,334-88-3) + 11-bromoundecanoic acid (2834-05-1) → 11-bromo-undecanoic acid methyl ester (6287-90-7)

Guidance literature:

In diethyl ether; at 0 ℃; for 0.5h; Inert atmosphere;

DOI:10.1021/jm401586a

Reference yield: 99.0%

methanol (67-56-1) + 11-bromoundecanoic acid (2834-05-1) → 11-bromo-undecanoic acid methyl ester (6287-90-7)

Guidance literature:

With acetyl chloride; at 20 ℃; for 3h;

DOI:10.1039/b806559d

Reference yield: 89.1%

11-bromoundecanoic acid (2834-05-1) → 11-bromo-undecanoic acid methyl ester (6287-90-7)

Guidance literature:

upstream raw materials:

methanol

11-bromoundecanoic acid

Methyl 10-undecenoate

diazomethane

Downstream raw materials:

11-(3,4,5-Triphenyl-pyrazol-1-yl)-undecanoic acid methyl ester

methyl 2-phenylselenenyl-11-bromoundecanoate

12,12-Bis-benzenesulfonyl-dodecanoic acid methyl ester

12-Isocyano-12-(toluene-4-sulfonyl)-triacontanoic acid methyl ester

Refernces

• 1、 Yasa, Sathyam Reddy,Kaki, Shiva Shanker,Poornachandra,Kumar, C. Ganesh,Penumarthy, Vijayalakshmi. "Synthesis, characterization, antimicrobial and biofilm inhibitory activities of new N-oxide esters". . p. 1689 - 1696. Retrieved 2017.
• 2、 Do, Muu N.,Erickson, Karen L.. "BRANCHED CHAIN MONO-GLYCEROL ETHERS FROM A TAIWANESE MARINE SPONGE OF THE GENUS Aaptos". . p. 5699 - 5702. Retrieved 1983.
• 3、 Yasa, Sathyam Reddy,Kaki, Shiva Shanker,Poornachandra,Kumar, C. Ganesh,Penumarthy, Vijayalakshmi. "Synthesis, characterization, antimicrobial and biofilm inhibitory studies of new esterquats". . p. 1978 - 1982. Retrieved 2016.
• 4、 Waugh, Kristy M.,Berlin, K. Darrell. "Studies in Lipid Mimics. Synthesis and Carbon-13 Relaxation Time Measurements (T1 Values) of Methyl Esters of ω-(2-Anthryl)alkanoic Acids". . p. 873 - 878. Retrieved 1984.
• 5、 Rawling, Tristan,Roseblade, Ariane,Roy, Ritik. "Expansion of the structure-activity relationship of branched chain fatty acids: Effect of unsaturation and branching group size on anticancer activity". . . Retrieved 2020/09/03.