DIMETHYL-1,1,1-D3 ETHER (GAS)

Base Information

• Chemical Name: DIMETHYL-1,1,1-D3 ETHER (GAS)
• CAS No.: 13725-27-4
• Molecular Formula: C2H3 D3 O
• Molecular Weight: 49.0452
• Mol file: 13725-27-4.mol

Synonyms:(Methylether)-1,1,1-d3 (6CI,7CI,8CI); Dimethyl ether-d3; Methyl methyl-d3 ether

Chemical Property of DIMETHYL-1,1,1-D3 ETHER (GAS)

Chemical Property:

• Vapor Pressure: 4780mmHg at 25°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: 0.722g/cm³
• LogP: 0.26260

Purity/Quality:

Dimethyl-1,1,1-d3Ether(gas) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DIMETHYL-1,1,1-D3 ETHER (GAS)

There total 12 articles about DIMETHYL-1,1,1-D3 ETHER (GAS) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Dimethyl ether (115-10-6,157621-61-9) + C3H6(2)H3O(1+) → trimethyloxonium cation (43625-65-6) + methyl trideuteriomethyl ether (13725-27-4)

Guidance literature:

at 270.9 ℃; Rate constant; other temp. investigated;

DOI:10.1021/j100342a032

Reference yield:

sodium methylate (124-41-4) + C13H8(2)H3S(1+)*BF4(1-) → dibenzothiophene (132-65-0) + methyl trideuteriomethyl ether (13725-27-4)

Guidance literature:

In methanol; at 10 ℃; Rate constant; Kinetics; α-deuterium isotope effect under various temperatures;

DOI:10.1021/ja00345a047

Reference yield:

C(2)H5O(1+) (108864-10-4) + bis(1,1-dimethoxyethyl) peroxide → deuteromethanol (1455-13-6) + methyl acetate-d3 (24704-57-2) + methyl trideuteriomethyl ether (13725-27-4) + ethyl acetate (141-78-6)

Guidance literature:

In d⁽⁴⁾-methanol;

upstream raw materials:

trimethyl phosphite

methoxide-d3 anion

Dimethyl ether

1,1,1-trideuteromethanol

Downstream raw materials:

Dimethyl ether

dimethyl ether-d6

Refernces

• 1、 Van Doorn,Nibbering. "". . p. 527,528-531, 533. Retrieved 1978.
• 2、 Musker,Stevens. "". . p. 3515. Retrieved 1968.
• 3、 Khazipov, Oleg V.,Nykytenko, Denys V.,Krasnyakova, Tatyana V.,Vdovichenko, Alexander N.,Fuentes Frias, Dario A.,Mitchenko, Serge A.. "Catalytic etherification of alcohols in Shilov system: C[sbnd]O versus C[sbnd]H bond activation". . p. 490 - 498. Retrieved 2016/12/16.
• 4、 Olmstead, William N.,Brauman, John I.. "Gas-Phase Nucleophilic Displacement Reactions". . p. 1653 - 1662. Retrieved 2007/10/03.