Methanesulfenyl chloride, trifluoro-

Base Information

• Chemical Name: Methanesulfenyl chloride, trifluoro-
• CAS No.: 421-17-0
• Molecular Formula: CCl F3 S
• Molecular Weight: 136.525
• Hs Code.: 2930909090
• European Community (EC) Number: 207-003-8
• UNII: V7EVX6QGK4
• DSSTox Substance ID: DTXSID4059962
• Nikkaji Number: J101.227D
• Wikidata: Q72511216
• Mol file: 421-17-0.mol

Synonyms:421-17-0;Methanesulfenyl chloride, trifluoro-;trifluoromethylsulphenyl chloride;trifluoromethyl thiohypochlorite;Trifluoromethylsulfenyl chloride;Perfluoromethylsulfenyl chloride;Trifluoromethanesulfenyl chloride;Trifluoromethanesulphenyl chloride;Methanesulfenylchloride, trifluoro-;EINECS 207-003-8;CClF3S;V7EVX6QGK4;trifluoromethylthio chloride;Trifluoro(chlorothio)methane;C-Cl-F3-S;Trifluoromethylsulphenylchloride;SCHEMBL1156948;trifluoromethyl hypochlorothioite;DTXSID4059962;trifluoromethane-sulfenyl chloride;trifluoromethane-sulphenyl chloride;MFCD00039306;AKOS006228475;FT-0600314

Chemical Property of Methanesulfenyl chloride, trifluoro-

Chemical Property:

• Vapor Pressure: 1850mmHg at 25°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 25.30000
• Density: 1.573g/cm³
• LogP: 2.39320
• Sensitive.: Lachrymatory
• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 135.9361334
• Heavy Atom Count: 6
• Complexity: 40.5

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Hazard Codes: T
• Statements: 26-34
• Safety Statements: 23-24/25-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(F)(F)(F)SCl

Technology Process of Methanesulfenyl chloride, trifluoro-

There total 54 articles about Methanesulfenyl chloride, trifluoro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

sodium fluoride (7681-49-4) + chlorothio-trichloro-methane (594-42-3) → Trifluoromethylsulfenyl chloride (421-17-0)

Guidance literature:

In further solvent(s); in tetramethylsulphone at 170-250°C;

DOI:10.1021/jo01081a050

Reference yield:

bis(trifluoromethylthio) amine (763-24-6) + sulfur dichloride (10545-99-0) → hydrogenchloride (7647-01-0,15364-23-5) + disulfur dichloride (10025-67-9) + Trifluoromethylsulfenyl chloride (421-17-0) + S4N3Cl

Guidance literature:

120°C;

Reference yield:

trifluoromethylsulfanyldichlorophosphine (1495-32-5) + chlorine (7782-50-5) → Trifluoromethylsulfenyl chloride (421-17-0) + phosphorus pentachloride (10026-13-8,874483-75-7) + phosphorus trichloride (7719-12-2,52843-90-0)

Guidance literature:

-78°C;

DOI:10.1039/jr9600001108

upstream raw materials:

chlorodifluoromethansulfenylchloride

Bis(trifluoromethyl)disulfid

mercury bis(trifluoromethanethiolate)

trifluoromethylmercapto carbamic acid chloride

Downstream raw materials:

2-Trifluormethylmercapto-furan

Bis(trifluoromethyl)disulfid

[(trifluoromethyl)disulfanyl]benzene

chlorotrifluoromethane

Refernces

• 1、 Wei, Jun,Bao, Kun,Qi, Chengcheng,Liu, Yao,Ni, Chuanfa,Sheng, Rong,Hu, Jinbo. "Transition-Metal-Free Electrophilic Fluoroalkanesulfinylation of Electron-Rich (Het)Arenes with Fluoroalkyl Heteroaryl Sulfones via C(Het)?S and S=O Bond Cleavage". supporting information. p. 5528 - 5533. Retrieved 2019/11/14.
• 2、 -. "A METHOD FOR PREPARATION OF PERFLUOROALKYL SULFENYL CHLORIDE". Page/Page column 17-18. . Retrieved 2011/07/30.