BENZYLTRIETHYLPHOSPHONIUM BROMIDE

Base Information

• Chemical Name: BENZYLTRIETHYLPHOSPHONIUM BROMIDE
• CAS No.: 7016-55-9
• Molecular Formula: C13H22P.Br
• Molecular Weight: 289.195
• Mol file: 7016-55-9.mol

Synonyms:benzyl-triethylphosphonium bromide;triethylbenzyl phosphonium bromide;

Chemical Property of BENZYLTRIETHYLPHOSPHONIUM BROMIDE

Chemical Property:

• PSA: 13.59000
• LogP: 1.26790

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BENZYLTRIETHYLPHOSPHONIUM BROMIDE

There total 6 articles about BENZYLTRIETHYLPHOSPHONIUM BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

benzyl bromide (100-39-0) + triethylphosphine (554-70-1) → benzyl-triethylphosphonium bromide (7016-55-9)

Guidance literature:

In dichloromethane; at 0 - 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/ejoc.200900634

Reference yield:

benzyl bromide (100-39-0) + triethylamine (121-44-8) → benzyltriethylammonium bromide (5197-95-5) + benzyl-triethylphosphonium bromide (7016-55-9)

Guidance literature:

With triethylphosphine; In diethyl ether; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1007/BF00954168

Reference yield:

benzyl bromide (100-39-0) + triethylphosphine (554-70-1) → benzyltriethylammonium bromide (5197-95-5) + benzyl-triethylphosphonium bromide (7016-55-9)

Guidance literature:

With triethylamine; In diethyl ether; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1007/BF00954168

upstream raw materials:

ethyl diethylphosphinothioite

benzyl bromide

triethylamine

triethylphosphine

Downstream raw materials:

trans-1-(3,4-methylenedioxyphenyl)-2-phenylethylene

(Z)-1-Phenyl-1-tridecene

(E)-1-phenyltridec-1-ene

(E)-β-(1-decyl)styrene

Refernces

• 1、 Frei, Reto,Breitbach, Anthony S.,Blackwell, Helen E.. "2-aminobenzimidazole derivatives strongly inhibit and disperse Pseudomonas aeruginosa biofilms". supporting information; experimental part. p. 5226 - 5229. Retrieved 2012/07/03.
• 2、 McNulty, James,Das, Priyabrata. "Highly Stereoselective and General Synthesis of (E)-Stilbenes and Alkenes by Means of an Aqueous Wittig Reaction". supporting information; experimental part. p. 4031 - 4035. Retrieved 2009/12/09.