Phosphoric acid, mono(4-nitrophenyl) monophenyl ester

Base Information

• Chemical Name: Phosphoric acid, mono(4-nitrophenyl) monophenyl ester
• CAS No.: 793-12-4
• Molecular Formula: C12H10NO6P
• Molecular Weight: 295.188
• Mol file: 793-12-4.mol

Synonyms:

Chemical Property of Phosphoric acid, mono(4-nitrophenyl) monophenyl ester

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phosphoric acid, mono(4-nitrophenyl) monophenyl ester

There total 9 articles about Phosphoric acid, mono(4-nitrophenyl) monophenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + O-phenyl phosphorodichloridate (770-12-7) → phenyl(p-nitrophenyl)phosphoric acid (793-12-4)

Guidance literature:

4-nitro-phenol; O-phenyl phosphorodichloridate; With pyridine; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;

With water; sodium hydrogencarbonate; In dichloromethane; for 1h; Saturated solution;

With hydrogenchloride; In water; pH=5;

DOI:10.1002/anie.200805843

Reference yield:

4-nitro-phenyl diphenyl phosphate (10359-36-1) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + diphenyl hydrogen phosphate (838-85-7) + phenyl(p-nitrophenyl)phosphoric acid (793-12-4) + phenol (108-95-2,27073-41-2)

Guidance literature:

With (ZnCR)2(ClO₄)3(OH); In water; acetonitrile; at 25 ℃; Rate constant; other reagents;

DOI:10.1021/ja00269a041

Reference yield:

bis(4 nitrophenyl) phenylphosphate (38873-96-0) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + phenyl(p-nitrophenyl)phosphoric acid (793-12-4)

Guidance literature:

With 1-aminodecane; water; decylamine hydrochloride; at 25 ℃; Further Variations:; Reagents; Kinetics;

DOI:10.1007/BF01457772

upstream raw materials:

4-nitro-phenyl diphenyl phosphate

Phenyl-phosphoramidic acid 4-nitro-phenyl ester phenyl ester

p-nitrophenyl phenyl phosphorochloridate

bis(4 nitrophenyl) phenylphosphate

Downstream raw materials:

4-nitro-phenol

phenyl monophosphate

phosphoric acid monophenyl ester

Refernces

• 1、 Babtie, Ann C.,Bandyopadhyay, Subhajit,Olguin, Luis F.,Hollfelder, Florian. "Efficient catalytic promiscuity for chemically distinct reactions". supporting information; experimental part. p. 3692 - 3694. Retrieved 2009/10/02.
• 2、 Gellman, Samuel H.,Petter, Russell,Breslow, Ronald. "Catalytic Hydrolysis of a Phosphate Triester by Tetracoordinated Zinc Complexes". . p. 2388 - 2394. Retrieved 2007/10/02.