CID 6327934

Base Information

• Chemical Name: CID 6327934
• CAS No.: 796-14-5
• Molecular Formula: C21H22Sn
• Molecular Weight: 393.116
• DSSTox Substance ID: DTXSID40310473
• Mol file: 796-14-5.mol

Synonyms:AC1L7NFP;796-14-5;DTXSID40310473

Chemical Property of CID 6327934

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 393.066528
• Heavy Atom Count: 22
• Complexity: 263

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)[Sn](C2=CC=C(C=C2)C)C3=CC=C(C=C3)C

Technology Process of CID 6327934

There total 2 articles about CID 6327934 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

lithium aluminium tetrahydride (16853-85-3) + tris(4-methylphenyl)tin(IV) chloride (32538-28-6) → tri(p-tolyl)tin hydride (796-14-5)

Guidance literature:

In diethyl ether; refluxing for 2.5 h;;

DOI:10.1021/jo01044a042

Reference yield:

borane (13283-31-3) + tetra(p-tolyl)tin (6746-22-1) → tri(p-tolyl)tin hydride (796-14-5)

Guidance literature:

With sodium hydroxide; water; dihydrogen peroxide; In tetrahydrofuran; water; to soln. of Sn compd. in THF added soln. of BH3 (B/Sn ratio 1/1) in THF under N2 at room temp., stirred 1 h, refluxed 1h, cooled to room temp., added H2O, added soln. of 3 M NaOH in 30% H2O2, stirred for 30 min; added Et2O, extd. (3 M NaOH), acidified with dil. HCl, extd. (Et2O);

DOI:10.1016/S0022-328X(00)98667-4

Reference yield: 93.0%

dimethyl(2,2'-bipyridine)platinum(II) (52594-52-2) + tri(p-tolyl)tin hydride (796-14-5) → cis,trans-[PtH(Me)(Sn(C6H4Me-4)3)2(BIPY)]

Guidance literature:

In methanol; stirring under N2 at room temp. for 1 h; evapn., addn. of hexane, washing with hexane; elem. anal.;

DOI:10.1016/S0022-328X(00)86654-1

upstream raw materials:

borane

tetra(p-tolyl)tin

lithium aluminium tetrahydride

tris(4-methylphenyl)tin(IV) chloride

Downstream raw materials:

tris(4-methylphenyl)tin(IV) bromide

tris(4-methylphenyl)tin(IV) iodide

(Z)-1-{2-(tri-p-tolylstannyl)vinyl}-1-cyclohexanol

(Z)-1-[2-(tri-p-tolylstannyl)vinyl]-1-cycloheptanol

Refernces