1,1'-[(Dichloromethanediyl)disulfonyl]dibenzene

Base Information

• Chemical Name: 1,1'-[(Dichloromethanediyl)disulfonyl]dibenzene
• CAS No.: 18087-00-8
• Molecular Formula: C13H10Cl2O4S2
• Molecular Weight: 365.2521
• NSC Number: 131066
• DSSTox Substance ID: DTXSID80299495
• Wikidata: Q82041939
• Mol file: 18087-00-8.mol

Synonyms:1,1'-[(dichloromethanediyl)disulfonyl]dibenzene;[benzenesulfonyl(dichloro)methyl]sulfonylbenzene;18087-00-8;NSC131066;DTXSID80299495;NSC-131066;Z56760596

Chemical Property of 1,1'-[(Dichloromethanediyl)disulfonyl]dibenzene

Chemical Property:

• Boiling Point: 527.8°Cat760mmHg
• Flash Point: 273°C
• Density: 1.52g/cm³
• XLogP3: 3.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 363.9397565
• Heavy Atom Count: 21
• Complexity: 496

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)S(=O)(=O)C(S(=O)(=O)C2=CC=CC=C2)(Cl)Cl

Technology Process of 1,1'-[(Dichloromethanediyl)disulfonyl]dibenzene

There total 3 articles about 1,1'-[(Dichloromethanediyl)disulfonyl]dibenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

phenyliodonium bis(phenylsulfonyl)-methylide (121434-38-6) → bis(phenylsulfonyl)dichloromethane (18087-00-8)

Guidance literature:

With N-chloro-succinimide; In dichloromethane; Ambient temperature;

DOI:10.1021/ja00310a072

Reference yield:

bis(phenylsulfonyl)methane (3406-02-8) → bis(phenylsulfonyl)dichloromethane (18087-00-8)

Guidance literature:

With pyridine; sulfuryl dichloride; In dichloromethane;

DOI:10.1021/jo00897a021

Reference yield:

bis(phenylsulfonyl)dibromomethane (18086-96-9) → bis(phenylsulfonyl)dichloromethane (18087-00-8)

Guidance literature:

Multi-step reaction with 2 steps

1: Na₂S₂O₃ / H₂O; acetone

2: SO₂Cl₂, Py / CH₂Cl₂

With pyridine; sulfuryl dichloride; sodium thiosulfate; In dichloromethane; water; acetone;

DOI:10.1021/jo00897a021

upstream raw materials:

phenyliodonium bis(phenylsulfonyl)-methylide

bis(phenylsulfonyl)methane

bis(phenylsulfonyl)dibromomethane

Refernces