ZINC PHTHALOCYANINE

Base Information

• Chemical Name: ZINC PHTHALOCYANINE
• CAS No.: 14320-04-8
• Molecular Formula: C32H16N8Zn
• Molecular Weight: 577.923
• Hs Code.: 29269095
• European Community (EC) Number: 238-262-5
• NCI Thesaurus Code: C79758
• Mol file: 14320-04-8.mol

Synonyms:Zinc, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, (SP-4-1)-;Zinc, [phthalocyaninato(2-)]- (8CI);29H,31H-Phthalocyanine, zinc complex;29H,31H-Phthalocyanine, zinc deriv.;CGP 55847;Ciaftalan zinc;Phthalocyaninatozinc;Zinc phthalocyanine complex;Zinc(2+) phthalocyaninate;Zinc(II) phthalocyanine;Phthalocyanine,zinc deriv. (6CI);

Chemical Property of ZINC PHTHALOCYANINE

Chemical Property:

• Appearance/Colour: purple powder
• Vapor Pressure: 0.01-1.8Pa at 20-475℃
• PSA: 99.94000
• Density: 1.614-1.62g/cm3 at 20℃
• LogP: 1.14850
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 576.078934
• Heavy Atom Count: 41
• Complexity: 1080

Purity/Quality:

98% ^*data from raw suppliers

Zinc phthalocyanine ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Dyes -> Phthalocyanine Dyes
• Canonical SMILES: C1=CC=C2C(=C1)C3=NC4=NC(=NC5=C6C=CC=CC6=C([N-]5)N=C7C8=CC=CC=C8C(=N7)N=C2[N-]3)C9=CC=CC=C94.[Zn+2]
• Uses: Zinc Phthalocyanine is used in preparation of Zinc Phthalocyanine-loaded Amphiphilic Phosphonium chitosan nanomicelles for enhancement of photodynamic therapy efficacy.

Technology Process of ZINC PHTHALOCYANINE

There total 58 articles about ZINC PHTHALOCYANINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

phthalonitrile (91-15-6) + zinc (7440-66-6) → zinc(II) phthalocyanine (14320-04-8)

Guidance literature:

With sodium methylate; In methanol; Sonication; Zn added to a methanol soln. containing an equivalent quantity of phthalonitrile and 5 drops of 30% soln of CH3ONa in methanol; flask put into an ultrasonic cleaner and maintained at 50°C for 24-72 h; blue product separated from unreacted metal by shaking and decanting with the solvent, washed with ethanol in Soxhlet equipment and dried in air; purity of 95-97%; elem. anal.;

DOI:10.1016/j.inoche.2004.10.006

Reference yield: 95.0%

zinc(II) acetate dihydrate (5970-45-6) + phthalonitrile (91-15-6) → zinc(II) phthalocyanine (14320-04-8)

Guidance literature:

In N,N-dimethyl-formamide; at 200 ℃; for 0.166667h; Microwaves;

Reference yield: 92.0%

zinc(II) acetate dihydrate (5970-45-6) + 29H,31H-Phthalocyanine (574-93-6) → zinc(II) phthalocyanine (14320-04-8)

Guidance literature:

With butyl(2-hydroxyethyl)dimethylammonium acetate; at 100 ℃; Ionic liquid; Inert atmosphere;

DOI:10.1080/00397911.2013.867505

upstream raw materials:

phthalonitrile

phthalimide

3-[4-(hydroxymethyl)phenoxy]phthalonitrile

4-[4-(hydroxymethyl)phenoxy]phthalonitrile

Downstream raw materials:

bis(triphenylphosphine)iminium nitrito(phralocyaninato)zincate hydrate

29H,31H-Phthalocyanine

29H,31H-phthalocyanine

Refernces

• 1、 Revuelta-Maza, Miguel á.,Torres, Tomás,Torre, Gema De La. "Synthesis and Aggregation Studies of Functional Binaphthyl-Bridged Chiral Phthalocyanines". . p. 8183 - 8186. Retrieved 2019.
• 2、 Cui, Li-Ying,Yang, Jin,Fu, Qiang,Zhao, Bao-Zhong,Tian, Lei,Yu, Hai-Ling. "Synthesis, crystal structure and characterization of a new zinc phthalocyanine complex". . p. 149 - 154. Retrieved 2007.
• 3、 Weiler, Ulrich,Mayer, Thomas,Jaegermann, Wolfram,Kelting, Christian,Schlettwein, Derck,Makarov, Sergey,Woì?hrle, Dieter. "Electronic energy levels of organic dyes on silicon: A photoelectron spectroscopy study of ZnPc, F16ZnPc, and ZnTPP on p-Si(111):H". . p. 19398 - 19403. Retrieved 2004.
• 4、 Kharisov,Garza-Rodriguez,Leija Gutierrez,Ortiz Mendez,Garcia Caballero,Tsivadze. "Preparation of non-substituted metal phthalocyanines at low temperature using activated Rieke zinc and magnesium". . p. 755 - 760. Retrieved 2005.
• 5、 Liang, Qian,Zhang, Miao,Zhang, Zhihui,Liu, Changhai,Xu, Song,Li, Zhongyu. "Zinc phthalocyanine coupled with UIO-66 (NH2) via a facile condensation process for enhanced visible-light-driven photocatalysis". . p. 123 - 130. Retrieved 2017.
• 6、 Pop,Winter,Freyer,Widdra,Hertel. "Photoelectron spectroscopy on thin films of extended zinc porphyrazines". . p. 7826 - 7833. Retrieved 2005.
• 7、 Imperatori, Patrizia,Paoletti, Anna Maria,Pennesi, Giovanna,Zanotti, Gloria. "Sustainable approaches to the synthesis of metallophthalocyanines in solution". . . Retrieved 2021.
• 8、 Iwatsu, Fumio,Kobayashi, Takashi,Uyeda, Natsu. "Solvent Effects on Crystal Growth and Transformation of Zinc Phthalocyanine". . p. 3223 - 3230. Retrieved 1980.
• 9、 Janczak, Jan,Kubiak, Ryszard,Bukowska, Ewa. "Isomorphic complexes formed by recrystallisation of M(II)Pc (M(II) = Mg, Mn and Zn) in liquid 2-amino-3-picoline". . p. 25 - 33. Retrieved 2009.
• 10、 Gerdes, Robert,Lapok, Lukasz,Tsaryova, Olga,Woehrle, Dieter,Gorun, Sergiu M.. "Rational design of a reactive yet stable organic-based photocatalyst". . p. 1098 - 1100. Retrieved 2009.