ARSINE, DICHLORO(p-NITROPHENYL)-

Base Information

• Chemical Name: ARSINE, DICHLORO(p-NITROPHENYL)-
• CAS No.: 51956-43-5
• Molecular Formula: C6H4AsCl2NO2
• Molecular Weight: 267.931
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID40199927
• Nikkaji Number: J62.306G
• Wikidata: Q83072952
• Mol file: 51956-43-5.mol

Synonyms:2-(di-n-propylamino)tetralin;N,N-dipropyl-2-amino-1,2,3,4-tetrahydronaphthalene;N,N-dipropyl-2-aminotetralin;N,N-dipropyl-2-aminotetralin hydrobromide;N,N-dipropyl-2-aminotetralin hydrochloride;N,N-dipropyl-2-aminotetralin hydrochloride, (R)-isomer;N,N-dipropyl-2-aminotetralin, (+-)-isomer;TL 68;TL-68

Chemical Property of ARSINE, DICHLORO(p-NITROPHENYL)-

Chemical Property:

• Vapor Pressure: 9.72E-05mmHg at 25°C
• Boiling Point: 349.1°Cat760mmHg
• Flash Point: 164.9°C
• PSA: 45.82000
• Density: g/cm³
• LogP: 2.29080
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 266.883503
• Heavy Atom Count: 12
• Complexity: 165

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1[N+](=O)[O-])[As](Cl)Cl

Technology Process of ARSINE, DICHLORO(p-NITROPHENYL)-

There total 2 articles about ARSINE, DICHLORO(p-NITROPHENYL)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

nitarsone (98-72-6) → dichloro-(4-nitro-phenyl)-arsine (51956-43-5)

Guidance literature:

With hydrogenchloride; sulfur dioxide; iodine;

Reference yield:

p-nitrobenzenediazonium (14368-49-1) → dichloro-(4-nitro-phenyl)-arsine (51956-43-5)

Guidance literature:

Multi-step reaction with 2 steps

1: alkali; sodium arsenite

2: sulfur dioxide; hydrochloric acid / 15 °C

With hydrogenchloride; trisodium arsenite; sulfur dioxide;

Reference yield: 77.4%

dichloro-(4-nitro-phenyl)-arsine (51956-43-5) + tert-butyl alcohol (75-65-0) → di-tert-butyl (p-nitrophenyl)arsonite

Guidance literature:

With triethylamine; In benzene; for 24h;

upstream raw materials:

nitarsone

p-nitrobenzenediazonium

Downstream raw materials:

bis-(4-nitro-phenyl)-arsinic acid

(4-nitro-phenyl)-dithioarsonous acid diphenyl ester

<4-Nitro-phenyl>-bis-methoxycarbonylmethyl-arsin

chloroethane

Refernces