Europium chloride [inci]

Base Information

• Chemical Name: Europium chloride [inci]
• CAS No.: 10025-76-0
• Molecular Formula: Cl3Eu
• Molecular Weight: 258.319
• Hs Code.: 2846902010
• UNII: LP6WL6W368
• Nikkaji Number: J95.966I
• Mol file: 10025-76-0.mol

Synonyms:EUROPIUM CHLORIDE [INCI];NNMXSTWQJRPBJZ-UHFFFAOYSA-K;AKOS015901809;E0707;H11382

Chemical Property of Europium chloride [inci]

Chemical Property:

• Appearance/Colour: powder
• Vapor Pressure: 33900mmHg at 25°C
• Melting Point: 850 °C(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 4.89 g/mL at 25 °C(lit.)
• LogP: 2.06850
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble in water. Soluble in dilute hydrochloric acid, acetone and alcohol. Slightly soluble in tetrahydrofuran.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 257.82779
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

99.99% ^*data from raw suppliers

Europium(III) chloride, anhydrous (99.9%-Eu) (REO) ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Eu+3]
• Uses: member of a family of moderate Lewis acids capable of acting as catalysts in selected oxidative and reductive processes,with particular utility in systems designed to exploit the chemistry of divalent and zerovalent reagents and organometallic intermediates. Europium(III) chloride is used as a starting material for the preparation of other europium salts. It is also used in preparation of europium(II)chloride by reduction in a gold boat using hydrogen gas. Further, it is also used to prepare organometallic compounds of europium.

Technology Process of Europium chloride [inci]

There total 23 articles about Europium chloride [inci] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

hydrogenchloride (7647-01-0,15364-23-5) + europium(III) oxide → europium(III) chloride (10025-76-0)

Guidance literature:

In hydrogenchloride; metal oxide treated with 1:1 hydrochloric acid; soln. filtered, evapd. to dryness, crystals dried in vaccum dessicator over CaCl2;

DOI:10.1081/SIM-120003800

Reference yield: 72.0%

aluminium chloride dimer + europium(III) oxide → aluminum oxochloride + europium(III) chloride (10025-76-0)

Guidance literature:

In neat (no solvent); Al2Cl6 prepd. from Al and Cl2; in Duran tube, at 400°C (Cl2); chemical vapour phase transport with Al2Cl6 from 400 to 310°C, 24 h;

Reference yield:

→ europium(III) chloride (10025-76-0)

Guidance literature:

upstream raw materials:

hydrogenchloride

thionyl chloride

aluminium trichloride

tetrachloromethane

Downstream raw materials:

tin(IV) chloride

Refernces

• 1、 Thorne,Jones,McCaw,Murdoch,Denning,Khaidukov. "Two-photon spectroscopy of europium (III) elpasolites". . p. 7851 - 7866. Retrieved 1999.
• 2、 Gospodinov,Stancheva. "Phase states of europium selenites in aqueous medium and in thermal analysis". . p. 221 - 226. Retrieved 1999.
• 3、 Suzuki, Itsuko S.,Suzuki, Masatsugu,Burr, Charles R.,Hwang, D. M.,Stumpp, Eberhard. "". . . Retrieved 1991.
• 4、 Peng, Chunyun,Zhang, Hongjie,Yu, Jiangbo,Meng, Qingguo,Fu, Lianshe,Li, Huanrong,Sun, Lining,Guo, Xianmin. "Synthesis, characterization, and luminescence properties of the ternary europium complex covalently bonded to mesoporous SBA-15". . p. 15278 - 15287. Retrieved 2005.
• 5、 Morais, Crislene R.S,Gouveia Souza, Ant?nio,Santa-Cruz, Petrus A. "Kinetic study of the thermal decomposition of Eu3+ with β-diketone ligands and 1,10-phenanthroline or 2,2-dipyridine". . p. 101 - 104. Retrieved 2002.
• 6、 Nocera, D. G.,Morss, L. R.,Fahey, J. A.. "". . p. 55 - 60. Retrieved 1980.
• 7、 Kalman, Ferenc K.,Baranyai, Zsolt,Toth, Imre,Banyai, Istvan,Kiraly, Robert,Bruecher, Ernoe,Aime, Silvio,Sun, Xiankai,Sherry, A. Dean,Kovacs, Zoltan. "Synthesis, potentiometric, kinetic, and NMR studies of 1,4,7,10- tetraazacyclododecane-1,7-bis(acetic acid)-4,10-bis(methylenephosphonic acid) (DO2A2P) and its complexes with Ca(II), Cu(II), Zn(II) and lanthanide(III) ions". . p. 3851 - 3862. Retrieved 2008.
• 8、 Francisco, Cristina S.,Stucchi, Elizabeth B.,de Abreu, Edson M.. "Luminescent properties of yttrium diphenylphosphinate activated by europium". . p. 234 - 237. Retrieved 2006.
• 9、 Liu, Beiping,Tan, Zhi-Cheng,Zhang, Dashun,Nan, Zhaodong,Sun, Lixian,Xu, Fen,Lan, Xiaozhen,Liang, Ping,Yu, Xiaomei. "Low-temperature heat capacity and thermodynamic properties of crystalline [Re2(Ala)4(H2O)8] (ClO4)6 (Re = Eu, Er; Ala = alanine)". . p. 31 - 37. Retrieved 2002.
• 10、 An, Bao-Li,Gong, Meng-Lian,Zhang, Ji-Ming,Zheng, Shao-Liang. "Synthesis, bright luminescence and crystal structure of a novel neutral europium complex". . p. 2719 - 2724. Retrieved 2003.