1-(methylsulfinyl)-3-nitrobenzene

Base Information

• Chemical Name: 1-(methylsulfinyl)-3-nitrobenzene
• CAS No.: 3272-42-2
• Molecular Formula: C₇H₇NO₃S
• Molecular Weight: 185.203
• Mol file: 3272-42-2.mol

Synonyms:

Chemical Property of 1-(methylsulfinyl)-3-nitrobenzene

Chemical Property:

• Vapor Pressure: 3.81E-05mmHg at 25°C
• Refractive Index: 1.636
• Boiling Point: 363.3 °C at 760 mmHg
• Flash Point: 173.5 °C
• Density: 1.43 g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-(methylsulfinyl)-3-nitrobenzene

There total 13 articles about 1-(methylsulfinyl)-3-nitrobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

1-(methylsulfanyl)-3-nitrobenzene (2524-76-7) → methyl 3-nitrophenyl sulfoxide (132016-29-6,146143-21-7,3272-42-2)

Guidance literature:

With dihydrogen peroxide; acetic acid; In methanol; water; at 20 ℃; for 24h;

DOI:10.1021/jm201214d

Reference yield:

1-(methylsulfanyl)-3-nitrobenzene (2524-76-7) → (+)-(S)-3-methylsulfinylnitrobenzene (132016-29-6,3272-42-2,146143-21-7) + (+)-(R)-3-methylsulfinylnitrobenzene (146143-21-7,3272-42-2,132016-29-6)

Guidance literature:

With dihydrogen peroxide; (salen)Mn(III)Cl complex 1; In acetonitrile; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;

DOI:10.1016/S0040-4039(00)60849-3

Reference yield:

1-(methylsulfanyl)-3-nitrobenzene (2524-76-7) → (+)-(S)-3-methylsulfinylnitrobenzene (132016-29-6,3272-42-2,146143-21-7) + (+)-(R)-3-methylsulfinylnitrobenzene (146143-21-7,3272-42-2,132016-29-6)

Guidance literature:

With dihydrogen peroxide; (salen)Mn(III)Cl complex 1; In acetonitrile; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;

DOI:10.1016/S0040-4039(00)60849-3

upstream raw materials:

1-(methylsulfanyl)-3-nitrobenzene

dimethyl sulfoxide

3-nitro-aniline

methyl 3-nitrophenyl sulfoxide

Downstream raw materials:

(+)-(S)-3-methylsulfinylnitrobenzene

(+)-(R)-3-methylsulfinylnitrobenzene

3-nitrophenyl thiocyanate

(RS)-N-(ethoxycarbonyl)-S-(3-{[5-bromo-pyrimindin-2-yl]amino}phenyl)-S-methylsulfoximide

Refernces

• 1、 Li, Min,Lou, Jiangli,Rao, Yijian,Yuan, Zhenbo,Zhang, Yan. "Emodinas a novel organic photocatalyst for selective oxidation of sulfides under mild conditions". . p. 19747 - 19750. Retrieved 2020/06/04.
• 2、 Pramanik, Mukund M. D.,Rastogi, Namrata. "Visible light catalyzed methylsulfoxidation of (het)aryl diazonium salts using DMSO". supporting information. p. 8557 - 8560. Retrieved 2016/07/13.