Indium(3+);triiodide

Base Information

• Chemical Name: Indium(3+);triiodide
• CAS No.: 13510-35-5
• Molecular Formula: I3In
• Molecular Weight: 495.534
• Hs Code.: 28276000
• UNII: 3Y156GSM7E
• Nikkaji Number: J43.828F
• Mol file: 13510-35-5.mol

Synonyms:indium(3+);triiodide;RMUKCGUDVKEQPL-UHFFFAOYSA-K

Chemical Property of Indium(3+);triiodide

Chemical Property:

• Melting Point: 210 °C
• PSA: 0.00000
• Density: 4.69 g/cm³
• LogP: 2.65710
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Sensitive.: Hygroscopic
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 495.6173
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Indium(III) iodide (99.999%-In) PURATREM ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 42/43-63
• Safety Statements: 22-26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [In+3].[I-].[I-].[I-]
• Uses: Indium(III) iodide is used to prepare vinyl and methyl indates which undergo regioselective reactions with cinnamyl bromide.1 Indium(III) iodide is used in chemical research.

Technology Process of Indium(3+);triiodide

There total 17 articles about Indium(3+);triiodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

indium (7440-74-6) + iodine (7553-56-2,12190-71-5,8031-47-8) → indium(III) iodide (13510-35-5)

Guidance literature:

In hexane; thin foil of In was suspended in degassed n-hexane under argon, 1.5 equiv. I2 was added, mixt. was refluxed for 1-3 h; elem. anal.;

Reference yield:

indium(II) iodide → indium (7440-74-6) + indium(III) iodide (13510-35-5)

Guidance literature:

With 1,2-bis-(diphenylphosphino)ethane; In benzene;

DOI:10.1139/v82-101

Reference yield:

indium(II) 2-methylbutane-2-thiolate → indium(III) iodide (13510-35-5)

Guidance literature:

With iodine; In acetonitrile; react. with I2 in CH3CN under dry N2; collection of solid, drying; elem. anal.;

upstream raw materials:

indium

iodine

indium(III) phosphide

InI₂⁽¹⁺⁾

Downstream raw materials:

InI₃((C₆H₄(OH))CHN(C₁₀H₇))

Dipp₂nacnacInI₂

[indium(III)(diiodide)(κ3-N(C6H3(Me)PPh2)2]

indium sulfide

Refernces

• 1、 Titov,Chusova,Stenin. "On thermodynamic characteristics of In-I system compounds thermodynamische daten von indiumiodid". . p. 1013 - 1018. Retrieved 1999.
• 2、 Callegari, Victor,Nellen, Philipp M.. "Spontaneous growth of uniformly distributed in nanodots and InI3 nanowires on InP induced by a focused ion beam". . p. 1665 - 1671. Retrieved 2008/10/09.
• 3、 Ranu, Brindaban C.,Hajra, Alakananda. "Indium triiodide catalysed one-step conversion of tetrahydropyranyl ethers to acetates with high selectivity". . p. 355 - 357. Retrieved 2007/10/03.