TIN(IV) FLUORIDE

Base Information

• Chemical Name: TIN(IV) FLUORIDE
• CAS No.: 7783-62-2
• Molecular Formula: F4Sn
• Molecular Weight: 194.704
• Hs Code.: 2826199090
• Wikipedia: Tin(IV) fluoride,Tin(IV)_fluoride
• Mol file: 7783-62-2.mol

Synonyms:Tinfluoride (SnF4) (6CI,7CI,8CI);Stannic fluoride;Tin tetrafluoride;Tin(4+)fluoride;Tin(IV) fluoride;

Chemical Property of TIN(IV) FLUORIDE

Chemical Property:

• Appearance/Colour: off-white powder
• Vapor Pressure: 922mmHg at 25°C
• Melting Point: 705 °C (subl.)
• Boiling Point: 19.5 °C at 760 mmHg
• PSA: 0.00000
• Density: 4,78 g/cm3
• LogP: 1.30000
• Sensitive.: Moisture Sensitive
• Water Solubility.: hydrolyzes in H2O [MER06]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 195.895815
• Heavy Atom Count: 5
• Complexity: 19.1

Purity/Quality:

99.9% ^*data from raw suppliers

Tin(IV) fluoride 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn,C
• Hazard Codes: Xn,C
• Statements: 20/21/22
• Safety Statements: 26-27-36-36/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: F[Sn](F)(F)F
• Uses: Friedel-Crafts catalyst. It is used as Friedel-Crafts catalyst.

Technology Process of TIN(IV) FLUORIDE

There total 56 articles about TIN(IV) FLUORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

fluorine (7782-41-4) + tin(IV) oxide → tin(IV) fluoride (7783-62-2)

Guidance literature:

In neat (no solvent); formation at fluorination of SnO2 with F2 at 500-550°C;;

DOI:10.1021/ja01637a040

Reference yield: 100.0%

Carbonyl fluoride (353-50-4) + tin(IV) oxide → tin(IV) fluoride (7783-62-2) + carbon dioxide (124-38-9,18923-20-1)

Guidance literature:

With cesium fluoride; In neat (no solvent); SnO2:COF2 = 1:4; mixt. heated in a stainless steel or monel cylinder at 220°C for 70 h in presence of a small amt. of CsF;

Reference yield: 83.0%

tin disulfide + sulfur tetrafluoride (7783-60-0) → tin(IV) fluoride (7783-62-2)

Guidance literature:

In neat (no solvent); formation in a closed reactor out of SnS2 and SF4 at slow heating to 150°C and reaction for 8 h at 300°C;; extraction with CS2;;

upstream raw materials:

tin

nitrosyl fluoride

chlorine trifluoride

fluorine

Downstream raw materials:

(7-(7-benzothiazol-2-yl-9,9-diethylfluoren-2-yl)-9,9-diethylfluoren-2-yl)diphenylamine

phosphorus pentafluoride

tin(IV) chloride

trifluorosilane

Refernces

• 1、 Davis, Martin F.,Levason, William,Reid, Gillian,Webster, Michael,Zhang, Wenjian. "The first examples of germanium tetrafluoride and tin tetrafluoride complexes with soft thioether coordination-synthesis, properties and crystal structures". . p. 533 - 538. Retrieved 2008.
• 2、 Haendler, H. M.,Bartram, S. F.,Bernard, W. J.,Kippax, D.. "". . p. 2179 - 2180. Retrieved 1954.
• 3、 Fischer,Mueller. "Synthesis and crystal structure of silver(II) fluorides AgMIVF6 (MIV = Sn, Ti, Pb, Pd, Pt, Rh)". . p. 445 - 452. Retrieved 2008/10/08.
• 4、 Bork,Hoppe. "On the constitution of PbF4 with structure refinement of SnF4". . p. 1557 - 1563. Retrieved 2008/10/09.