Benzohydroximic acid, (E)-

Base Information

• Chemical Name: Benzohydroximic acid, (E)-
• CAS No.: 7340-17-2
• Molecular Formula: C9H11NO2
• Molecular Weight: 165.192
• NSC Number: 113533,113523
• Nikkaji Number: J1.122.412A
• Mol file: 7340-17-2.mol

Synonyms:Benzohydroximic acid, ethyl ester, (E)-;NSC113533;anti-Ethylbenzohydroximate;(z)-ethyl benzohydroximate;Benzenecarboximidic acid, N-hydroxy-, ethyl ester, (E)-;Benzohydroximic acid, (E)-;Benzohydroximic acid, (Z)-;(E)-Benzohydroximic acid ethyl ester;NSC113523;NSC-113523;NSC-113533;Benzohydroximic acid, ethyl ester, (Z)-;Benzenecarboximidic acid, ethyl ester, (E)-;Benzenecarboximidic acid, ethyl ester, (Z)-;Benzenecarboximidic acid, N-hydroxy-, ethyl ester, (Z)-;7340-49-0

Chemical Property of Benzohydroximic acid, (E)-

Chemical Property:

• Vapor Pressure: 0.00339mmHg at 25°C
• Boiling Point: 270.3°Cat760mmHg
• Flash Point: 117.3°C
• Density: 1.05g/cm³
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 165.078978594
• Heavy Atom Count: 12
• Complexity: 151

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=NO)C1=CC=CC=C1
• Isomeric SMILES: CCO/C(=N\O)/C1=CC=CC=C1

Technology Process of Benzohydroximic acid, (E)-

There total 14 articles about Benzohydroximic acid, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

Thiobenzoic acid O-ethyl ester (936-61-8) → ethyl N-hydroxybenzimidate (7340-17-2)

Guidance literature:

With hydroxylamine hydrochloride; sodium acetate; In ethanol; for 4h; Ambient temperature;

Reference yield:

(Z)-N-(4-methoxy-benzoyloxy)-benzimidic acid ethyl ester → ethyl N-hydroxybenzimidate (7340-17-2) + 4-methoxybenzoic acid (100-09-4)

Guidance literature:

ethyl-antibenzhydroximic acid-anisate;

Reference yield:

ethyl-antibenzhydroximic acid-phosphate → phosphoric acid (86119-84-8,7664-38-2) + ethyl N-hydroxybenzimidate (7340-17-2)

Guidance literature:

upstream raw materials:

(E)-N-benzoyloxy-benzimidic acid ethyl ester

(Z)-ethyl benzohydroximate

Thiobenzoic acid O-ethyl ester

benzimidic acid ethyl ester

Downstream raw materials:

N-hydroxybenzenecarboximidamide

2-phenyl-oxazole-4-carboxylic acid ethyl ester

ethyl N-<(2'-ethoxycarbonylvinyl)oxy>benzimidate

ethyl N-(<1',2'-bis(methoxycarbonyl)vinyl>oxy)benzimidate

Refernces

• 1、 Brion, Jean-Daniel,Reynaud, Pierre,Kirkiacharian, Serge. "A New Convenient Route to Alkyl Hydroximates and their ON-Alkyl Derivatives (Alkyl N-Hydroxy- and N-Alkoxycarboximidates)". . p. 220 - 222. Retrieved 2007/10/02.