Medina

Base Information

• Chemical Name: Medina
• CAS No.: 14168-44-6
• Molecular Formula: CH4 N4 O4
• Molecular Weight: 136.067
• Hs Code.: 2928000090
• DSSTox Substance ID: DTXSID80161800
• Wikidata: Q25999260
• Metabolomics Workbench ID: 53966
• Mol file: 14168-44-6.mol

Synonyms:methylenedinitramine

Chemical Property of Medina

Chemical Property:

• Refractive Index: 1.5000 (estimate)
• Boiling Point: 323.4°Cat760mmHg
• Flash Point: 149.4°C
• PSA: 115.70000
• Density: 1.542g/cm³
• LogP: 0.33470
• XLogP3: 0.9
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 2
• Exact Mass: 136.02325462
• Heavy Atom Count: 9
• Complexity: 96.7

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(N[N+](=O)[O-])N[N+](=O)[O-]

Technology Process of Medina

There total 12 articles about Medina which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) → MEDINA (14168-44-6)

Guidance literature:

With nitramide; sulfuric acid; In water; at -10 - -5 ℃; for 0.333333h;

DOI:10.1023/A:1015334703526

Reference yield: 89.0%

N,N′-dinitrourea (176501-96-5) → MEDINA (14168-44-6)

Guidance literature:

With formaldehyd; sulfuric acid; at 65 - 70 ℃; for 0.333333h;

DOI:10.1023/A:1022555327527

Reference yield: 87.0%

N,N'-dinitromethylenediamine dipotassium salt → MEDINA (14168-44-6)

Guidance literature:

With hydrogenchloride; In diethyl ether; at 0 - 5 ℃; for 3h;

DOI:10.1023/A:1022555327527

upstream raw materials:

methanol

nitro-bis-(nitroamino-methyl)-amine; sodium-salt

bis-(formyl-nitro-amino)-methane

N,N'-bis-hydroxymethyl-N,N'-dinitro-methylenediamine

Downstream raw materials:

1,3-dibenzyl-5-nitro-hexahydro-[1,3,5]triazine

3,5-dinitro-[1,3,5]oxadiazinane

1-Nitro-3,5-dioxa-1-azacyclohexane

formaldehyd

Refernces

• 1、 Lobanova,Il'yasov,Popov,Sataev. "Chemistry of urea nitro derivatives: II. Synthesis of nitramide from N,N′-dinitrourea. New reactions of nitramide". . p. 1 - 6. Retrieved 2007/10/03.
• 2、 Il'yasov,Lobanova,Popov,Sataev. "Chemistry of urea nitro derivatives: IV. Reaction of N,N′ -dinitrourea with formaldehyde". . p. 1739 - 1743. Retrieved 2007/10/03.