Trimethyl 2,2':6',2''-terpyridine-4,4',4''-tricarboxylate

Base Information

• Chemical Name: Trimethyl 2,2':6',2''-terpyridine-4,4',4''-tricarboxylate
• CAS No.: 330680-46-1
• Molecular Formula: C21H17N3O6
• Molecular Weight: 407.382
• Hs Code.: 29333990
• Mol file: 330680-46-1.mol

Synonyms:[2,2':6',2''-Terpyridine]-4,4',4''-tricarboxylic acid, trimethyl ester;2,2':6',2''-Terpyridine-4,4',4''-tricarboxylate de triméthyle;

Chemical Property of Trimethyl 2,2':6',2''-terpyridine-4,4',4''-tricarboxylate

Chemical Property:

• Melting Point: 239.0 to 243.0 °C
• Boiling Point: 603.8 °C at 760 mmHg
• PKA: 0.47±0.42(Predicted)
• Flash Point: 319 °C
• PSA: 117.57000
• Density: 1.3 g/cm³
• LogP: 2.56540
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

99.0% ^*data from raw suppliers

Trimethyl 2,2′:6′,2″-terpyridine-4,4′,4″-tricarboxylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Use Description: Trimethyl 2,2':6',2''-terpyridine-4,4',4''-tricarboxylate is a chemical compound with versatile applications in different fields. In coordination chemistry and materials science, it is often used as a ligand to form coordination complexes with various metal ions. These complexes have applications in catalysis, photophysics, and materials development, including the fabrication of luminescent materials and sensors. Additionally, in the field of chemical synthesis, this compound can serve as a building block for the creation of more complex molecules, contributing to the development of novel chemical compounds with specific properties. Its role in these fields underscores its significance in advancing coordination chemistry, materials research, and the synthesis of functional materials and catalysts for various applications.

Technology Process of Trimethyl 2,2':6',2''-terpyridine-4,4',4''-tricarboxylate

There total 3 articles about Trimethyl 2,2':6',2''-terpyridine-4,4',4''-tricarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

methanol (67-56-1) + 4,4',4-tricarboxy-2,2':6',2-terpyridine (216018-58-5) → trimethyl 2,2:6′,2''-terpyridine-4,4',4''-tricarboxylate (330680-46-1)

Guidance literature:

With sulfuric acid; for 6h; Reflux;

DOI:10.1039/c0dt01417f

Reference yield:

4,4’,4”-triethyl-2,2’:6’,2”-terpyridine (33354-77-7) → trimethyl 2,2:6′,2''-terpyridine-4,4',4''-tricarboxylate (330680-46-1)

Guidance literature:

Multi-step reaction with 2 steps

1.1: H₂SO₄; K₂Cr₂O₇

1.2: 36 percent / 50percent aq. HNO₃ / 5 h / Heating

2.1: 72 percent / H₂SO₄ / 72 h / Heating

With potassium dichromate; sulfuric acid;

DOI:10.1021/ja003299u

Reference yield:

4,4',4-trimethyl-2,2':6',2-terpyridine (33354-75-5) → trimethyl 2,2:6′,2''-terpyridine-4,4',4''-tricarboxylate (330680-46-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 41 percent / CrO₃, H₂SO₄ / 75 °C

2: 72 percent / H₂SO₄ / 72 h / Heating

With chromium(VI) oxide; sulfuric acid;

DOI:10.1039/a703277c

upstream raw materials:

methanol

4,4',4-tricarboxy-2,2':6',2-terpyridine

4,4’,4”-triethyl-2,2’:6’,2”-terpyridine

4,4',4-trimethyl-2,2':6',2-terpyridine

Downstream raw materials:

4,4',4-tricarboxy-2,2':6',2-terpyridine

trichloro(trimethyl-4,4',4''-tricarboxylate-2,2':6',2''-terpyridine)ruthenium

Refernces

• 1、 -. "A method of manufacturing a sensitizing dye-based optical ruthenic". Paragraph 0058. . Retrieved 2017/03/18.
• 2、 Giribabu, Lingamallu,Bessho, Takeru,Srinivasu, Mareedu,Vijaykumar, Challuri,Soujanya, Yarasi,Reddy, Veeranagari Gopal,Reddy, Paidi Yella,Yum, Jun-Ho,Graetzel, Michael,Nazeeruddin, Mohammad Khaja. "A new familiy of heteroleptic ruthenium(ii) polypyridyl complexes for sensitization of nanocrystalline TiO2 films". experimental part. p. 4497 - 4504. Retrieved 2011/06/22.