2,2,2-TRICHLOROETHYL ACRYLATE

Base Information

• Chemical Name: 2,2,2-TRICHLOROETHYL ACRYLATE
• CAS No.: 44925-09-9
• Molecular Formula: C5H5Cl3O2
• Molecular Weight: 203.452
• Hs Code.: 2916129000
• Mol file: 44925-09-9.mol

Synonyms:2,2,2-Trichloroethylacrylate;

Chemical Property of 2,2,2-TRICHLOROETHYL ACRYLATE

Chemical Property:

• Vapor Pressure: 0.103mmHg at 25°C
• Refractive Index: 1.4738
• Boiling Point: 222.2 °C at 760 mmHg
• Flash Point: 91.8 °C
• PSA: 26.30000
• Density: 1,376 g/cm³
• LogP: 2.08580

Purity/Quality:

98%min ^*data from raw suppliers

2,2,2-TrichloroethylAcrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,2,2-TRICHLOROETHYL ACRYLATE

There total 2 articles about 2,2,2-TRICHLOROETHYL ACRYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1,1-trichloroethanol (115-20-8) + acryloyl chloride (814-68-6,25189-84-8) → acrylate de trichloro-2,2,2 ethyle (44925-09-9)

Guidance literature:

With triethylamine; p-benzoquinone; In benzene;

Reference yield:

1,1,1-trichloroethanol (115-20-8) + acrylic acid (79-10-7) → acrylate de trichloro-2,2,2 ethyle (44925-09-9)

Guidance literature:

With sulfuric acid; hydroquinone; In benzene; Heating; several alcohols investigated;

DOI:10.1016/S0022-1139(00)85059-9

Reference yield: 64.0%

acrylate de trichloro-2,2,2 ethyle (44925-09-9) + benzaldehyde (100-52-7) → 3-phenyl-3-hydroxy-2-methylene-propanoic acid 2,2,2-trichloroethyl ester (144261-73-4)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; for 36h; Ambient temperature;

DOI:10.1016/S0040-4020(01)88227-2

upstream raw materials:

1,1,1-trichloroethanol

acryloyl chloride

acrylic acid

Downstream raw materials:

3-phenyl-3-hydroxy-2-methylene-propanoic acid 2,2,2-trichloroethyl ester

(2S,3R)-2-{3,4-bis(triisopropylsilyloxy)phenyl}-7-(methoxymethoxy)-4-{(E)-3-oxo-3-(2,2,2-trichloroethoxy)prop-1-en-1-yl}-2,3-dihydrobenzofuran-3-carboxylic acid

(2S,3R)-2-{3,4-bis(triisopropylsilyloxy)phenyl}-7-hydroxy-4-{(E)-3-oxo-3-(2,2,2-trichloroethoxy)prop-1-en-1-yl}-2,3-dihydrobenzofuran-3-carboxylic acid

Refernces

• 1、 Boutevin,Rigal,Rousseau,Bosc. "-". . p. 47 - 73. Retrieved 2007/10/02.