Silver methanesulfonate, 98%

Base Information

• Chemical Name: Silver methanesulfonate, 98%
• CAS No.: 2386-52-9
• Molecular Formula: CH3AgO3S
• Molecular Weight: 202.967
• Hs Code.: 28432900
• NSC Number: 83223
• ChEMBL ID: CHEMBL1996983
• Mol file: 2386-52-9.mol

Synonyms:NCI60_041828;SCHEMBL564772;Silver methanesulfonate, 98%;CHEMBL1996983;CAA38652;NSC83223;NSC-83223;WLN: WS1&O &-AG- &9/5;CS-0035248

Chemical Property of Silver methanesulfonate, 98%

Chemical Property:

• Appearance/Colour: white to beige or light grey crystalline powder
• Melting Point: 252-256 °C(lit.)
• PSA: 65.58000
• Density: 1.511 g/cm3
• LogP: 0.24220
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Sensitive.: Light Sensitive
• Water Solubility.: Soluble in water, alcohol, ether and benzene. Slightly soluble in toluene, o-chlorotoluene and ethyl disulfide. Insoluble in hex
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 202.89321
• Heavy Atom Count: 6
• Complexity: 92.6

Purity/Quality:

99.9% ^*data from raw suppliers

Silver methanesulfonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn, Xi
• Hazard Codes: Xi,Xn
• Statements: 36/37/38-20/21/22
• Safety Statements: 26-36-36/37/39-22

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CS(=O)(=O)O.[Ag]
• Uses: Gold Catalysts—21st Century'Gold Rush' Catalyst for: .Heterocyclization reactions . CO2-mediated rearrangement of propargyl alcohols for the synthesis of a,?-unsaturated ketones and esters Silver methanesulfonate is used as a catalyst for heterocyclization reactions. Further, it is used in the synthesis of unsaturated ketones and esters.

Technology Process of Silver methanesulfonate, 98%

There total 4 articles about Silver methanesulfonate, 98% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

methanesulfonic acid (75-75-2,98527-29-8) + silver(l) oxide (20667-12-3) → silver methanesulfonate (2386-52-9)

Guidance literature:

In water; at 90 ℃; for 3h;

Reference yield: 83.0%

methanesulfonic acid (75-75-2,98527-29-8) + silver carbonate → silver methanesulfonate (2386-52-9)

Guidance literature:

In water; (N2); addn. of aq. soln. of methanesulfonic acid to aq. suspn. of silvercompd. at 20°C, stirring for 1 h at 20°C; filtration through celite, evapn. at 50°C in vac.;

DOI:10.1016/j.poly.2008.04.041

Reference yield: 25.0%

methanesulfonic acid (75-75-2,98527-29-8) + silver nitrate → silver methanesulfonate (2386-52-9)

Guidance literature:

In water; stoich. amts.; crystn. on slow evapn., manual sepn. of needles, washing (Me2CO, Et2O), drying (reduced pressure, over P2O5); elem. anal.;

DOI:10.1039/DT9770000578

upstream raw materials:

methanesulfonic acid

silver(l) oxide

Downstream raw materials:

1,4-Di-O-methansulfonylerythrit

DL-Threitol-1,4-bis-methansulfonat

2,3,4,5-Tetra-O-acetyl-1,6-di-O-methansulfonylgalactit

Methylsulfonyloxy-acetamid

Refernces

• 1、 Tao, Xian,Shen, Ke-Cheng,Shen, Ying-Zhong. "Syntheses, X-ray structures and CVD studies of trimethylphosphite stabilized silver(I) methanesulfonates". . p. 2681 - 2684. Retrieved 2011.
• 2、 -. "TRIFUNCTIONAL ADDITIVES FOR ELECTROLYTE COMPOSITION FOR LITHIUM BATTERIES". Page/Page column 26-27. . Retrieved 2018/08/20.
• 3、 Glushko, Valentina,Blokhina, Lidiya,Sadovskaya, Natalya,Kozhukhov, Vadim. "Nonaqueous preparation of stable silver nanoparticles dispersions from organic sulfonic acids". . p. 789 - 797. Retrieved 2016/07/06.