4-Decenal

Base Information

• Chemical Name: 4-Decenal
• CAS No.: 65405-70-1
• Molecular Formula: C10H18O
• Molecular Weight: 154.252
• Hs Code.: 2912190090
• European Community (EC) Number: 265-741-6
• UNII: KZ74B5801J
• DSSTox Substance ID: DTXSID0052338,DTXSID0067555
• Nikkaji Number: J133.178G,J307.396C
• Wikidata: Q27282519
• Metabolomics Workbench ID: 120032
• Mol file: 65405-70-1.mol

Synonyms:trans-4-Decen-1-al;65405-70-1;4-Decenal;(E)-dec-4-enal;trans-4-decenal;(E)-4-Decenal;4-trans-Decenal;4-Decenal, (E)-;4-Decenal, (4E)-;Dec-4-enal;30390-50-2;FEMA No. 3264;4-Decene-1-al;(4E)-dec-4-enal;UNII-KZ74B5801J;KZ74B5801J;EINECS 265-741-6;trans4-Decenal;Trans 4 Decenal;trans-dec-4-enal;(4e)-4-decenal;4E-Decen-1-al;4-Decenal,(4E)-;DECENAL [INCI];(E)-4-decen-1-al;(E) - 4 - decenal;4-DECENAL [FHFI];4-DECENAL, TRANS-;SCHEMBL1626853;SCHEMBL1626855;DTXSID0052338;DTXSID0067555;CWRKZMLUDFBPAO-UHFFFAOYSA-N;MFCD00065447;AKOS015916319;LS-2657;Disodium4-formylbenzene-1,3-disulphonate;2-CHLORO-1-METHYLPYRIDINIUMBROMIDE;BS-23871;A835101;Q27282519

Chemical Property of 4-Decenal

Chemical Property:

• Appearance/Colour: colorless liquid
• Vapor Pressure: 12.8Pa at 20℃
• Refractive Index: 1.442
• Boiling Point: 200.1 °C at 760 mmHg
• Flash Point: 81.7 °C
• PSA: 17.07000
• Density: 0.835 g/cm³
• LogP: 3.10200
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 7
• Exact Mass: 154.135765193
• Heavy Atom Count: 11
• Complexity: 105

Purity/Quality:

99.9% ^*data from raw suppliers

trans-4-Decen-1-al ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 37/39-26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCC=CCCC=O
• Isomeric SMILES: CCCCC/C=C/CCC=O

Technology Process of 4-Decenal

There total 21 articles about 4-Decenal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1,1-dimethoxy-4Z-decene (68133-80-2) → (Z)-4-decenal (30390-50-2,65405-70-1,21662-09-9)

Guidance literature:

With hydrogenchloride; In acetone; for 4h; Ambient temperature;

Reference yield: 94.0%

trans-4-decen aldehyde dimethyl acetal (1118608-56-2) → trans-4-decenal (65405-70-1)

Guidance literature:

With acetic acid; In acetone; at 60 ℃; for 6h; Reagent/catalyst; Temperature;

Reference yield: 89.0%

(Z)-4-decen-1-ol (57074-37-0) → (Z)-4-decenal (30390-50-2,65405-70-1,21662-09-9)

Guidance literature:

(Z)-4-decen-1-ol; With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane; at -78 ℃; for 2h; Inert atmosphere;

With triethylamine; In dichloromethane; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1002/anie.201300739

upstream raw materials:

(Z)-4-decen-1-ol

1,1-dimethoxy-4Z-decene

1,1-dimethoxy-8-tosyloxy-(4Z)-octene

(Z)-4-decenoic acid ethyl ester

Downstream raw materials:

(Z)-dec-4-enoic acid

(4E,6E,10Z)-hexadeca-4,6,10-trien-1-ol

(2R,3S,6E)-2,3-dihydroxy-2,3-O-isopropylidene-1-phenyl-6-dodecen-1-one

(2R,3R,6E)-2,3-dihydroxy-2,3-O-isopropylidene-1-phenyl-6-dodecen-1-one

Refernces

• 1、 Jiang, Ying,Sun, Bing,Fang, Wan-Yin,Qin, Hua-Li. "A Transition-Metal-Free One-Pot Cascade Process for Transformation of Primary Alcohols (RCH2OH) to Nitriles (RCN) Mediated by SO2F2". supporting information. p. 3190 - 3194. Retrieved 2019/05/21.
• 2、 -. "Synthesis method for trans-4-decenal". . . Retrieved 2017/09/01.