Bis((6-broMopyridin-2-yl)Methyl)aMine

Base Information

• Chemical Name: Bis((6-broMopyridin-2-yl)Methyl)aMine
• CAS No.: 1265139-77-2
• Molecular Formula: C12H11Br2N3
• Molecular Weight: 357.04384
• Mol file: 1265139-77-2.mol

Synonyms:Bis((6-broMopyridin-2-yl)Methyl)aMine

Chemical Property of Bis((6-broMopyridin-2-yl)Methyl)aMine

Chemical Property:

• PSA: 37.81000
• LogP: 3.68230
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C

Purity/Quality:

99% ^*data from raw suppliers

Bis((6-bromopyridin-2-yl)methyl)amine >95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Bis((6-broMopyridin-2-yl)Methyl)aMine

There total 2 articles about Bis((6-broMopyridin-2-yl)Methyl)aMine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C18H14Br2N4O4S (1206455-34-6) → bis-(6-bromo-pyridin-2-ylmethyl)-amine (1265139-77-2)

Guidance literature:

With potassium carbonate; thiophenol; In N,N-dimethyl-formamide; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1039/b917692f

Reference yield:

6-bromo-2-pyridinecarbaldehyde (34160-40-2) → bis-(6-bromo-pyridin-2-ylmethyl)-amine (1265139-77-2) + (6-bromopyridin-2-yl)methanamine (188637-63-0)

Guidance literature:

6-bromo-2-pyridinecarbaldehyde; With polymer-bound 4-methoxybenzhydrylamine; sodium tris(acetoxy)borohydride; acetic acid; In 1,2-dichloro-ethane; at 20 ℃; for 48h;

With trifluoroacetic acid; In dichloromethane; water; at 20 ℃; for 4h;

DOI:10.1016/j.tetlet.2007.01.077

upstream raw materials:

6-bromo-2-pyridinecarbaldehyde

C₁₈H₁₄Br₂N₄O₄S

Refernces

• 1、 Drewry, Joel A.,Fletcher, Steven,Hassan, Haider,Gunning, Patrick T.. "Novel asymmetrically functionalized bis-dipicolylamine metal complexes: Peripheral decoration of a potent anion recognition scaffold". supporting information; experimental part. p. 5074 - 5077. Retrieved 2010/04/04.