trans-Mevinphos

Base Information

• Chemical Name: trans-Mevinphos
• CAS No.: 298-01-1
• Molecular Formula: C7H13 O6 P
• Molecular Weight: 224.15
• European Community (EC) Number: 206-417-6,206-051-7
• UNII: 3L63962IYU
• DSSTox Substance ID: DTXSID7042481
• Nikkaji Number: J193.785E,J2.270E
• Wikidata: Q27257497
• Mol file: 298-01-1.mol

Synonyms:trans-Mevinphos;(Z)-Mevinphos;338-45-4;trans-Phosdrin;beta-Mevinphos;methyl (Z)-3-dimethoxyphosphoryloxybut-2-enoate;Mevinphos, (Z)-;EINECS 206-417-6;UNII-3L63962IYU;3L63962IYU;CROTONIC ACID, 3-HYDROXY-, METHYL ESTER, DIMETHYL PHOSPHATE, (Z)-;Methyl 3-((dimethoxyphosphinyl)oxy)isocrotonate;Mevinphos (ISO);Mevinphos [ISO];2-Butenoic acid, 3-((dimethoxyphosphinyl)oxy)-, methyl ester, (2Z)-;2-Butenoic acid, 3-((dimethoxyphosphinyl)oxy)-, methyl ester, (Z)-;Mevinphos, Inhalable;Phosdrin (Mevinphos);Mevinphos;(Phosdrin);PHD (CHRIS Code);cis-Mevinphos (old RN);(E)-Mevinphos (cis-butenoic acid);C7-H13-O6-P;2-Butenoic acid, 3-[(dimethoxyphosphinyl)oxy]-, methyl ester, (2Z)-;2-Butenoic acid, 3-[(dimethoxyphosphinyl)oxy]-, methyl ester, (Z)-;2-Carbomethoxy-1-methylvinyl dimethyl ph;Mevinphos isomer 2;MEVINPHOS, TRANS-;Methyl 3-((dimethoxyphosphinyl)oxy)-2-butenoate (9CI);Methyl 3-hydroxycrotonate dimethyl phosphate ester (8CI);SCHEMBL3429514;DTXSID7042481;GEPDYQSQVLXLEU-WAYWQWQTSA-N;(Z)-Mevinphos (trans-butenoic acid);CIS-MEVINPHOS PESTANAL 50 MG;CIS-MEVINPHOS PESTANAL 50 MG;LS-55589;methyl 3-(dimethoxyphosphinyloxy)-crotonate;Methyl 3-[(dimethoxyphosphinyl)oxy]crotonate;W-109521;Q27257497

Chemical Property of trans-Mevinphos

Chemical Property:

• Vapor Pressure: 0.0323mmHg at 25°C
• Melting Point: 21 °C
• Refractive Index: 1.437
• Boiling Point: 243.4°Cat760mmHg
• Flash Point: 115.1°C
• PSA: 80.87000
• Density: 1.216g/cm³
• LogP: 1.48070
• Storage Temp.: 2-8°C
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 224.04497513
• Heavy Atom Count: 14
• Complexity: 263

Purity/Quality:

99% ^*data from raw suppliers

(E)-Mevinphos solution 100?μg/mL in acetonitrile, PESTANAL?, analytical standard ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T+,N,Xn,F
• Hazard Codes: T+,N,Xn,F
• Statements: 27/28-50/53-36-20/21/22-11
• Safety Statements: 23-28-36/37-45-60-61-16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=CC(=O)OC)OP(=O)(OC)OC
• Isomeric SMILES: C/C(=C/C(=O)OC)/OP(=O)(OC)OC

Technology Process of trans-Mevinphos

There total 3 articles about trans-Mevinphos which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl 2-chloroacetoacetate (4755-81-1,935731-92-3) + phosphorous acid trimethyl ester (121-45-9) → (E)-mevinphos (298-01-1) + dimethyl 2-carbomethoxy-1-methylvinyl phosphate (338-45-4)

Guidance literature:

Reference yield:

3-dimethoxyphosphoryloxy-cis-crotonic acid benzyl ester (2703-61-9) → (E)-mevinphos (298-01-1)

Guidance literature:

With 1,4-dioxane; palladium on activated charcoal; acetic acid; Hydrogenation_.Behandlung des Reaktionsprodukts mit Diazomethan in Aether;

Reference yield:

→ (E)-mevinphos (298-01-1)

Guidance literature:

(techn.);

DOI:10.1021/jo01068a077

upstream raw materials:

3-dimethoxyphosphoryloxy-cis-crotonic acid benzyl ester

methyl 2-chloroacetoacetate

phosphorous acid trimethyl ester

Downstream raw materials:

dimethylphosphoric acid