2-Methoxyethyl acrylate

Base Information

• Chemical Name: 2-Methoxyethyl acrylate
• CAS No.: 3121-61-7
• Molecular Formula: C6H10 O3
• Molecular Weight: 130.144
• Hs Code.: 29161290
• European Community (EC) Number: 221-499-3,817-997-0
• NSC Number: 24153
• UN Number: 2810,1992
• UNII: 515K4I683Y
• DSSTox Substance ID: DTXSID7025554
• Nikkaji Number: J55.297F
• Wikidata: Q27260866
• Mol file: 3121-61-7.mol

Synonyms:2-METHOXYETHYL ACRYLATE;3121-61-7;Methoxyethyl acrylate;2-methoxyethyl prop-2-enoate;32171-39-4;2-Propenoic acid, 2-methoxyethyl ester;Ethylene glycol methyl ether acrylate;Methyl cellosolve acrylate;2-Methoxyethoxy acrylate;Ethylene glycol monomethyl ether acrylate;2-Methoxyethanol, acrylate;Acrylic acid, 2-methoxyethyl ester;Sipomer MCA;Glycol monomethyl ether acrylate;Acrylic acid, 2-methoxyethoxy ester;2-Methoxyethylacrylate;Ethanol, 2-methoxy-, acrylate;2-Propenioc acid, 2-methoxyethyl ester;NSC 24153;EINECS 221-499-3;BRN 1754333;AI3-15726;UNII-515K4I683Y;NSC-24153;515K4I683Y;EC 221-499-3;MFCD00803685;Methoxyethyl acrylate(13cp(25 degrees c));mPEG-Acrylate;Ageflex MEA;Acryl-PEG;Acrylic Acid 2-Methoxyethyl Ester;methoxyethylacrylate;MFCD00048149;2-methyoxyethyl acrylate;Acrylic acid 2-methoxyethyl;SCHEMBL38483;WLN: QVYU1&2O1;WLN: 1U1VO2O1;DTXSID7025554;HFCUBKYHMMPGBY-UHFFFAOYSA-;METHOXYETHYL ACRYLATE, 2-;2-METHOXYETHYL 2-PROPENOATE;NSC24153;AKOS005206914;CS-W011111;LS-1172;Ethylene glycol monomethy ether acrylate;BS-42697;Ethylene glycol methyl ether acrylate, 98%;FT-0612840;2-Methoxyethyl Acrylate (stabilized with MEHQ);E77141;F77854;2-Methoxyethyl Acrylate, (stabilized with MEHQ);EN300-1718841;J-018279;Q27260866;Ethylene glycol methyl ether acrylate, contains 50-100 ppm MEHQ as inhibitor, 98%

Chemical Property of 2-Methoxyethyl acrylate

Chemical Property:

• Appearance/Colour: Clear colorless liquid with a sharp musty odor.
• Vapor Pressure: 3.62mmHg at 25°C
• Melting Point: -30°C
• Refractive Index: n20/D 1.427(lit.)
• Boiling Point: 56 ºC (12 mmHg)
• Flash Point: 60 ºC
• PSA: 35.53000
• Density: 1.012
• LogP: 0.36200
• Storage Temp.: 2-8°C(protect from light)
• Solubility.: Soluble in water
• Water Solubility.: 144g/L at 20℃
• XLogP3: 0.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 130.062994177
• Heavy Atom Count: 9
• Complexity: 98.5
• Transport DOT Label: Poison

Purity/Quality:

98% ^*data from raw suppliers

2-Methoxyethyl Acrylate (stabilized with MEHQ) >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T,C
• Statements: 20/22-24-41-61-60-48/22-43-34
• Safety Statements: 16-26-36/37/39-45-53-27/28-23

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: COCCOC(=O)C=C

Technology Process of 2-Methoxyethyl acrylate

There total 4 articles about 2-Methoxyethyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2-methoxy-ethanol (109-86-4,95507-80-5) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → 2-methoxyethyl acrylate (3121-61-7,28628-64-0)

Guidance literature:

With 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; di(n-butyl)tin oxide; In 2-Methylpentane; cyclohexane; at 85 - 100 ℃; for 12h; Temperature; Solvent;

Reference yield:

2-methoxy-ethanol (109-86-4,95507-80-5) + acryloyl chloride (814-68-6,25189-84-8) → 2-methoxyethyl acrylate (3121-61-7,28628-64-0)

Guidance literature:

With triethylamine; In chloroform; at 10 ℃; for 12h;

DOI:10.1016/S0040-4020(01)88227-2

Reference yield:

2-methoxy-ethanol (109-86-4,95507-80-5) + ethyl acrylate (140-88-5,9003-32-1) → 2-methoxyethyl acrylate (3121-61-7,28628-64-0)

Guidance literature:

With copper; toluene-4-sulfonic acid; hydroquinone; Abdestillieren des entstandenen Aethanols als Azeotrop mit Aethylacrylat;

DOI:10.1021/jo01158a019

upstream raw materials:

2-methoxy-ethanol

acrylic acid methyl ester

ethyl acrylate

acryloyl chloride

Downstream raw materials:

3-phenyl-3-hydroxy-2-methylene-propanoic acid 2-methoxyethyl ester

dipentaerythritol hexaacrylate

2,2-bis(hydroxymethyl)-1,3-propanediyl diacrylate

pentaerythritol tetraacrylate

Refernces

• 1、 -. "PROCESS FOR PREPARING 4-HYDROXYBUTYL ACRYLATE". Paragraph 0630; 0631; 0632; 0633; 0634. . Retrieved 2015/04/22.