Barium manganate

Base Information

• Chemical Name: Barium manganate
• CAS No.: 7787-35-1
• Deprecated CAS: 150993-75-2
• Molecular Formula: BaMnO4
• Molecular Weight: 256.26
• Hs Code.: 28416900
• European Community (EC) Number: 232-109-6
• UNII: R6Q81342Z4
• DSSTox Substance ID: DTXSID801046691
• Wikipedia: Barium manganate
• Wikidata: Q4280210
• Mol file: 7787-35-1.mol

Synonyms:Barium manganate;7787-35-1;Barium manganate(VI);Manganic acid (H2MnO4), barium salt (1:1);UNII-R6Q81342Z4;barium(2+);dioxido(dioxo)manganese;EINECS 232-109-6;R6Q81342Z4;Barium manganese oxide (BaMnO4);MFCD00011514;Ba.H2MnO4;Barium manganate, 90%;Ba.H2-Mn-O4;ZZCNKSMCIZCVDR-UHFFFAOYSA-N;DTXSID801046691;BARIUM MANGANATE(VI) [MI];AKOS015833391;C.I. 77110;FT-0622571;Manganic acid (H2MnO4) barium salt (1:1);Q4280210

Chemical Property of Barium manganate

Chemical Property:

• Appearance/Colour: blue to dark blue-black fine crystalline powder
• PSA: 80.26000
• Density: 4.85 g/cm³
• LogP: -0.47520
• Sensitive.: Moisture Sensitive
• Water Solubility.: Slightly soluble in water
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 256.822949
• Heavy Atom Count: 6
• Complexity: 62.2

Purity/Quality:

99%, ^*data from raw suppliers

Barium manganate, 90% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): OXn
• Hazard Codes: Xn,O
• Statements: 20/22-8
• Safety Statements: 28-28A

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [O-][Mn](=O)(=O)[O-].[Ba+2]
• Description: Barium manganate (chemical formula BaMnO4) is a type of manganates in which the manganese is in a +6 oxidation state. It is obtained by heating manganese dioxide with barium carbonate or nitrate, or by precipitating potassium manganate with barium chloride.1 Barium manganate gives a green pigment, which was used to make manganese blue. Barium manganate can be used in the oxidation of a variety of functional groups efficiently and selectively: alcohols to carbonyls, alcohols to aldehydes, diols to lactones, thiols to disulfides, aromatic amines to azo-compounds, hydroquinone to p-benzoquinone, benzylamine to benzaldehyde, etc. 2,3
• Uses: As pigment in fresco painting instead of Scheele's green because not so poisonous as latter. As mild oxidizing agent in organic synthesis. Useful for the selective oxidation of diols.