N,N'-Dimethylethylenediamine

Base Information

• Chemical Name: N,N'-Dimethylethylenediamine
• CAS No.: 110-70-3
• Molecular Formula: C4H12N2
• Molecular Weight: 88.1527
• Hs Code.: 29212900
• European Community (EC) Number: 203-793-3
• UNII: JBC5EX42TL
• DSSTox Substance ID: DTXSID4058730
• Nikkaji Number: J25.736B
• Wikidata: Q27966855
• Mol file: 110-70-3.mol

Synonyms:dimethylethylenediamine;N,N'-dimethylethylenediamine

Chemical Property of N,N'-Dimethylethylenediamine

Chemical Property:

• Appearance/Colour: colorless liquid
• Vapor Pressure: 15.5mmHg at 25°C
• Melting Point: 1.63°C (estimate)
• Refractive Index: n20/D 1.431(lit.)
• Boiling Point: 120 °C at 760 mmHg
• PKA: 10.54±0.10(Predicted)
• Flash Point: 83 °F
• PSA: 24.06000
• Density: 0.785 g/cm³
• LogP: 0.20700
• Storage Temp.: Flammables area
• Sensitive.: Air Sensitive
• Solubility.: Miscible with chloroform and dichloromethane.
• XLogP3: -0.6
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 88.100048391
• Heavy Atom Count: 6
• Complexity: 17.5

Purity/Quality:

99% ^*data from raw suppliers

N,N’-Dimethylethanediamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 10-34-20/21/22
• Safety Statements: 26-36/37/39-45-16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Nitrogen Compounds -> Amines, Aliphatic
• Canonical SMILES: CNCCNC
• Uses: Has a DNA binding effect N,N'-Dimethylethylenediamine is used in DNA binding effect. It is used to enhance the adsorption of carbon dioxide. It acts as a ligand and form coordination complex such as dinitrato(N,N'-dimethyl-1,2-ethanediamine)copper(II) and dichloro(1,4-bis-(diphenyl phosphino)butane)-(1,2-ethylenediamine)ruthenium(II).

Technology Process of N,N'-Dimethylethylenediamine

There total 30 articles about N,N'-Dimethylethylenediamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

1,3-dimethyl-2-imidazolidinone (80-73-9) → N,N`-dimethylethylenediamine (110-70-3)

Guidance literature:

With potassium hydroxide; at 140 ℃; Reagent/catalyst; Large scale;

Reference yield: 85.0%

1-methylhydantoin (6843-45-4) → N,N`-dimethylethylenediamine (110-70-3)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; for 72h; Heating; Argon;

DOI:10.1021/jo00161a021

Reference yield: 48.0%

N,N′-(ethane-1,2-diyl)bis(N,4-dimethylbenzenesulfonamide) (66821-82-7) → N,N`-dimethylethylenediamine (110-70-3)

Guidance literature:

With sulfuric acid; In water; at 90 - 100 ℃;

upstream raw materials:

(2-hydroxyethyl)(methyl)amine

N,N'-dimethyl-N,N'-bis-(4-nitroso-phenyl)-ethylenediamine

1,4-dimethyl-1,4-diazabicyclo[2.2.2]octane-1,4-diium hydroxide

N-methyl-2-chloroethylamine

Downstream raw materials:

1,3-dimethylimidazolidine

N,N'-Dimethyl-N,N'-bis-(phenylacetyl)-aethylendiamin

1-Triphenylsilyl-2,5-dimethyl-1-bora-2,5-diazolidin

1,3-dimethyl-2-phenyl-1,3,2-diazaphospholidine-2-oxide

Refernces

• 1、 Kankaanperae, Alpo,Scharlin, Pirketta,Kuusisto, Ilona,Kallio, Riitta,Bernoulli, Emma. "Ureas and amides as dipolar aprotic solvents in highly basic media. The dependence of kinetic basicity on solvent composition". . p. 169 - 174. Retrieved 1999.
• 2、 Pelckmans, Michiel,Vermandel, Walter,Van Waes, Frederik,Moonen, Kristof,Sels, Bert F.. "Low-Temperature Reductive Aminolysis of Carbohydrates to Diamines and Aminoalcohols by Heterogeneous Catalysis". . p. 14540 - 14544. Retrieved 2017/10/23.