Tetraphenylborate

Base Information

• Chemical Name: Tetraphenylborate
• CAS No.: 4358-26-3
• Molecular Formula: C24H20BNa
• Molecular Weight: 319.234
• UNII: 8TYC18K6NX
• DSSTox Substance ID: DTXSID801336454
• Nikkaji Number: J323.075I
• Wikipedia: Tetraphenylborate
• Wikidata: Q2016367
• ChEMBL ID: CHEMBL587884
• Mol file: 4358-26-3.mol

Synonyms:Ammonium Salt Tetraphenylborate;Kalignost;Potassium Salt Tetraphenylborate;Sodium Salt, Tetraphenylborate;Sodium Tetraphenylborate;Sodium, Tetraphenylboron;Tetraphenylborate;Tetraphenylborate Sodium Salt;Tetraphenylborate, Ammonium Salt;Tetraphenylborate, Barium Salt (2:1);Tetraphenylborate, Potassium Salt;Tetraphenylborate, Sodium;Tetraphenylboron;Tetraphenylboron Sodium

Chemical Property of Tetraphenylborate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 29.46000
• Density: g/cm³
• LogP: 1.58470
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 319.1658058
• Heavy Atom Count: 25
• Complexity: 301

Purity/Quality:

98%Min ^*data from raw suppliers

TETRAPHENYLBORATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: [B-](C1=CC=CC=C1)(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of Tetraphenylborate

There total 3 articles about Tetraphenylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acetylacetonato(N,N,N',N'-tetramethylenediamine)copper(II) tetraphenylborate → tetraphenylborate anion (4358-26-3) + {Cu(tmen)(acac)}(1+)

Guidance literature:

With N,N-dimethyl-formamide; In 1,2-dichloro-ethane; the copper(II) complex was mixed with the reagent in 1,2-dichloroethane at ambient temp.; the concn. of the complex being 5.85x(10-3) M and the base concn. varying from twofold to approx. 115-fold excess; monitored by UV-visible spectrophotometry; Kinetics;

Reference yield:

tribenzylzirconium(IV)(η6-phenyl)triphenylborate → tetraphenylborate anion (4358-26-3)

Guidance literature:

With C₄H₈O; In dichloromethane; Addn. of THF to CH2Cl2 soln. of Zr-compd.; NMR spectroscopy.;

DOI:10.1039/c39900001038

Reference yield:

→ tetraphenylborate anion (4358-26-3)

Guidance literature:

Downstream raw materials:

C₂₄H₂₀B^(1-)*C₅H₁₅N₄⁽¹⁺⁾

1,1'-dimethylcobalticinium tetraphenylborate

[Cr(η-benzene)2](BPh4)

biphenyl

Refernces