diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate

Base Information

• Chemical Name: diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate
• CAS No.: 135654-49-8
• Molecular Formula: CF₃O₃S*C₁₄H₁₂F₃S
• Molecular Weight: 418.381
• Mol file: 135654-49-8.mol

Synonyms:diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate

Chemical Property of diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate

There total 2 articles about diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

diphenyl sulfide (139-66-2) + 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate (100422-07-9) → diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate (135654-49-8)

Guidance literature:

In dichloromethane; for 2h; Ambient temperature;

DOI:10.1246/bcsj.64.2008

Reference yield: 84.0%

diphenyl sulfide (139-66-2) + 2,2,2-trifluoroethyl trifluoromethanesulphonate (6226-25-1) → diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate (135654-49-8)

Guidance literature:

at 150 ℃; for 30h; Sealed tube;

DOI:10.1021/acs.joc.7b00951

Reference yield: 99.0%

diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate (135654-49-8) + 4-methoxycarbonylphenylboronic acid (99768-12-4) → methyl 4-phenylbenzoate (720-75-2)

Guidance literature:

With bis(tri-t-butylphosphine)palladium⁽⁰⁾; sodium hydrogencarbonate; In N,N-dimethyl-formamide; at 60 ℃; for 6h; Inert atmosphere; Glovebox; Sealed tube;

DOI:10.1016/j.tet.2016.10.018

upstream raw materials:

diphenyl sulfide

2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate

2,2,2-trifluoroethyl trifluoromethanesulphonate

Refernces

• 1、 Song, Hai-Xia,Wang, Shi-Meng,Wang, Xiao-Yan,Han, Jia-Bin,Gao, Ying,Jia, Su-Jiao,Zhang, Cheng-Pan. "Solvent-free synthesis of alkyl and fluoroalkyl sulfonium salts from sulfides and fluoroalkyl trifluoromethanesulfonates". . p. 131 - 140. Retrieved 2016.
• 2、 -. "PESTICIDALLY ACTIVE AZOLE-AMIDE COMPOUNDS". Page/Page column 93; 94. . Retrieved 2020/09/30.
• 3、 -. "N-[1-(5-BROMO-2-PYRIMIDIN-2-YL-1,2,4-TRIAZOL-3-YL)ETHYL]-2-CYCLOPROPYL-6-(TRIFLUOROMETHYL)PYRIDINE-4-CARBOXAMIDE DERIVATIVES AND RELATED COMPOUNDS AS INSECTICIDES". Page/Page column 79; 80; 81. . Retrieved 2020/10/17.