Manganese(III)acetylacetonate

Base Information

• Chemical Name: Manganese(III)acetylacetonate
• CAS No.: 14284-89-0
• Molecular Formula: C15H21MnO6
• Molecular Weight: 352.266
• Hs Code.: 29141900
• European Community (EC) Number: 238-188-3
• Mol file: 14284-89-0.mol

Synonyms:14284-89-0;Manganese(III)acetylacetonate;Manganese(3+);(Z)-4-oxopent-2-en-2-olate;(Z)-4-hydroxypent-3-en-2-one;manganese;tris(((Z)-4-oxopent-2-en-2-yl)oxy)manganese;MFCD00000023;Mn(acac)3;AKOS025311027;H10683;Manganese(III) acetylacetonate, technical grade;Manganese(III) acetylacetonate, technical, >=95% (KT)

Chemical Property of Manganese(III)acetylacetonate

Chemical Property:

• Appearance/Colour: black crystalline powder
• Melting Point: 159-161 °C (dec.)(lit.)
• Boiling Point: 187.6 °C at 760 mmHg
• Flash Point: 71.9 °C
• PSA: 102.42000
• LogP: 1.66350
• Sensitive.: Hygroscopic
• Solubility.: Soluble in benzene, ethyl acetate
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 355.095332
• Heavy Atom Count: 22
• Complexity: 380

Purity/Quality:

98%,99%, ^*data from raw suppliers

ManganicAcetylacetonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 22-36/37/38-20/21/22
• Safety Statements: 36/37/39-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Mn]
• Isomeric SMILES: C/C(=C/C(=O)C)/O.C/C(=C/C(=O)C)/O.C/C(=C/C(=O)C)/O.[Mn]
• Uses: It is mainly used as a solvent in paint and a precursor to vitamin E.

Technology Process of Manganese(III)acetylacetonate

There total 9 articles about Manganese(III)acetylacetonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.1%

manganese (7439-96-5) + acetylacetone (123-54-6,81235-32-7) → manganese(III) acetylacetonate (14284-89-0)

Guidance literature:

With tert-butylammonium hexafluorophosphate(V); In acetylacetone; Electrochem. Process; tetra-n-butylammonium hexafluorophosphate added to dry acetylacetone, Mnelectrode; evapn. under vac., residue washed twice with hexane and twice with petroleum ether;

DOI:10.1080/15533170701748548

Reference yield: 87.0%

potassium permanganate (7722-64-7) + acetylacetone (123-54-6,81235-32-7) → manganese(III) acetylacetonate (14284-89-0)

Guidance literature:

In water; for 0.25h; Heating / reflux;

Reference yield: 87.0%

potassium permanganate (7722-64-7) → manganese(III) acetylacetonate (14284-89-0)

Guidance literature:

With (CH₃CO)2CH₂; In water; dissolving of powdered KMnO4 in water by slight warming, filtration, addn. of excess of distilled acetylacetone with vigorous stirring, stirring for 5 min over a steam-bath, allowing to cool for 10 min; filtration, washing several times with acetylacetone-water, vac. drying, recrystn. (benzene then light petroleum addn.), cooling to 0°C,elem. anal.;

DOI:10.1039/DT9820000669

upstream raw materials:

potassium permanganate

acetylacetone

manganese

manganese(ll) chloride

Downstream raw materials:

4-acetyl-3-methyl-6-phenyl-1,2-dioxan-3-ol

3-Acetyl-4-hydroxy-3-hexene-2,5-dione

benzophenone

5,5-diphenyldihydrofuran-2(3H)-one

Refernces

• 1、 Bhattacharjee, Manabendra N.,Chaudhuri, Mihir K.,Khathing, Darlando T.. "Direct Synthesis of Tris(acetylacetonato)manganese(III)". . p. 669 - 670. Retrieved 1982.
• 2、 Barnartt et al.. "". . p. 763. Retrieved 1958.
• 3、 Long,Lagowski. "The direct electrochemical synthesis of transition metal acetylacetonates". . p. 813 - 815. Retrieved 2008/10/09.