1-Benzylcycloheptene

Base Information

• Chemical Name: 1-Benzylcycloheptene
• CAS No.: 15537-52-7
• Molecular Formula: C₁₄H₁₈
• Molecular Weight: 186.297
• Mol file: 15537-52-7.mol

Synonyms:1-Benzylcycloheptene

Chemical Property of 1-Benzylcycloheptene

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 1-Benzylcycloheptene

There total 8 articles about 1-Benzylcycloheptene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

N,N,N--trimethyl--1--phenylmethanaminium trifluoromethanesulfonate (260783-80-0) + 1-cycloheptenyl acetate (14477-74-8) → 1-Benzylcycloheptene (15537-52-7)

Guidance literature:

With manganese; nickel(II) bromide 2-methoxyethyl ether complex; bathophenanthroline; sodium acetate; In N,N-dimethyl-formamide; at 80 ℃; for 24h;

DOI:10.1055/s-0039-1691525

Reference yield: 97.0%

(2-Benzenesulfonyl-2-benzyl-cycloheptyl)-dimethyl-phenyl-silane → 1-Benzylcycloheptene (15537-52-7)

Guidance literature:

With (n-Bu)4F; In tetrahydrofuran; Heating;

DOI:10.1016/0040-4039(95)00701-D

Reference yield:

Fluxema (14286-84-1) → 3-Dimethylamino-1-propanol (3179-63-3) + 1-Benzylcycloheptene (15537-52-7) + 1-benzylcycloheptan-1-ol (4006-73-9) + (Cycloheptylidenmethyl)benzol (15537-53-8)

Guidance literature:

In water; at 95 ℃; Mechanism; Rate constant; Thermodynamic data; further temperatures and different pH-s; ΔE(excit.);

DOI:10.1248/cpb.29.1398

upstream raw materials:

1-benzylcycloheptan-1-ol

oxalic acid

Fluxema

benzyl chloride

Downstream raw materials:

cycloheptyl-cyclohexyl-methane

Refernces

• 1、 Kim, Seong Heon. "Conversion of vinyl sulfones to regiospecifically functionalized trisubstituted olefins". . p. 4013 - 4014. Retrieved 1995.