Ceric ammonium nitrate

Base Information

• Chemical Name: Ceric ammonium nitrate
• CAS No.: 16774-21-3
• Molecular Formula: CeN8H8O6N18
• Molecular Weight: 548.226
• Hs Code.: 3822 00 00
• Mol file: 16774-21-3.mol

Synonyms:Ammoniumhexanitratocerate(IV) (6CI);Ammonium hexanitratocerate;Cerium diammoniumhexanitrate;Diammonium hexanitratocerate;NSC 215187;NSC 4313;ammonium cerium(IV) nitrate;Ammonium ceric nitrate;

Chemical Property of Ceric ammonium nitrate

Chemical Property:

• Appearance/Colour: yellow-orange crystals
• Vapor Pressure: 49.8mmHg at 25°C
• Melting Point: 107-108 °C
• Boiling Point: 83oC at 760 mmHg
• Flash Point: 87oC
• PSA: 414.10000
• Density: 1.10 g/cm³
• LogP: 2.13520
• Storage Temp.: 0-6°C
• Solubility.: 919-1020g/l
• Water Solubility.: 1410 G/L (20 ºC)

Purity/Quality:

98% ^*data from raw suppliers

Ceric ammonium nitrate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi,O,Xn
• Hazard Codes: Xi,O,Xn
• Statements: 8-36/37/38-36/38-41-22
• Safety Statements: 26-36-17-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Physical properties: Reddish-orange monoclinic crystals; very soluble in water.
• Uses: Ceric ammonium nitrate is used as a volumetric oxidizing reagent in many oxidation-reduction titrations. Cerium(IV) ion is a strong oxidant similar to permanganate ion. It is the most widely-used primary standard among all Ce(IV) compounds. Other applications of this compound are in organic oxidation reactions; and as a catalyst in polymerization of olefins. Used as oxidimetric standard. A strongly oxidizing cerium preparation

Technology Process of Ceric ammonium nitrate

There total 1 articles about Ceric ammonium nitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ammonium nitrate + cerous nitrate → ammonium cerium (IV) nitrate (16774-21-3)

Guidance literature:

With dihydrogen peroxide;

DOI:10.1039/c6ra12725h

Reference yield: 96.0%

ammonium cerium (IV) nitrate (16774-21-3) + sodium t-butanolate (865-48-5) → sodium nitrate (7631-99-4) + Ce2(OCMe3)4(μ-OCMe3)3(μ3-OCMe3)2Na (122423-62-5) + tert-butyl alcohol (75-65-0)

Guidance literature:

In tetrahydrofuran; byproducts: NH3; exclusion of air and water, stirred for 2 h; filtered (NaNO3), removal of solvent from filtrate, extn. (hexane), removal of solvent; elem. anal.;

Reference yield: 90.0%

ammonium cerium (IV) nitrate (16774-21-3) + 1,3-bis(3,5-bis(trifluoromethyl)phenyl)propane-1,3-dione → C76H28CeF48O8

Guidance literature:

1,3-bis(3,5-bis(trifluoromethyl)phenyl)propane-1,3-dione; With sodium hydroxide; In ethanol; for 0.0833333h;

ammonium cerium (IV) nitrate; In ethanol; for 0.25h;

Downstream raw materials:

2-(1,1-dimethylethyl)-6-(1,1-dimethyl-2-hydroxyethyl)-1,4-benzoquinone

sodium nitrate

nitrogen

oxygen

Refernces