trans-1-methyl-4-(1-methylvinyl)cyclohex-2-en-1-ol

Base Information

• Chemical Name: trans-1-methyl-4-(1-methylvinyl)cyclohex-2-en-1-ol
• CAS No.: 7212-40-0
• Molecular Formula: C₁₀H₁₆O
• Molecular Weight: 152.236
• Mol file: 7212-40-0.mol

Synonyms:2-Cyclohexen-1-ol,1-methyl-4-(1-methylethenyl)-, trans-; p-Mentha-2,8-dien-1-ol, stereoisomer(8CI); cis-p-Menth-2,8-diene-1-ol

Chemical Property of trans-1-methyl-4-(1-methylvinyl)cyclohex-2-en-1-ol

Chemical Property:

• Vapor Pressure: 0.029mmHg at 25°C
• Boiling Point: 216.873°C at 760 mmHg
• PKA: 14.66±0.40(Predicted)
• Flash Point: 86.957°C
• PSA: 20.23000
• Density: 0.947g/cm³
• LogP: 2.27970

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trans-1-methyl-4-(1-methylvinyl)cyclohex-2-en-1-ol

There total 15 articles about trans-1-methyl-4-(1-methylvinyl)cyclohex-2-en-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

Nerol (106-25-2) → trans-p-mentha-2,8-dien-1-ol (3886-78-0,4017-73-6,7212-40-0,22771-44-4,22972-51-6,52154-82-2,82769-01-5)

Guidance literature:

With tris(p-bromophenyl)amine cation radical; In acetonitrile; for 2h; Ambient temperature;

DOI:10.1039/a705326f

Reference yield: 61.0%

Geraniol (106-24-1) → trans-p-mentha-2,8-dien-1-ol (3886-78-0,4017-73-6,7212-40-0,22771-44-4,22972-51-6,52154-82-2,82769-01-5)

Guidance literature:

With tris(p-bromophenyl)amine cation radical; In acetonitrile; for 2h; Mechanism; Ambient temperature; also nerol;

DOI:10.1039/a705326f

Reference yield:

α-pinene epoxide (1686-14-2,25488-94-2) → (+)-p-mentha-2,8-dien-1-ol (22771-44-4,3886-78-0,4017-73-6,7212-40-0,22972-51-6,52154-82-2,82769-01-5) + campholenyc aldehyde (4501-58-0,23727-15-3,91200-86-1,91819-58-8) + isocampholenic aldehyde (33171-49-2,56270-99-6,3899-09-0) + pinocarveol (547-61-5,1674-08-4,2158-49-8,3917-59-7,5947-36-4,6712-79-4,19889-99-7,19894-98-5) + (4R,6R)-carveol (99-48-9,1197-06-4,1197-07-5,2102-58-1,2102-59-2,5157-78-8,5503-11-7,7632-16-8,18383-51-2,22567-18-6,20307-86-2) + trans-2-caren-4-ol (4017-82-7,52153-53-4,62532-46-1,88390-12-9,103063-10-1,6617-35-2)

Guidance literature:

With Fe/MCM-41(N₂); for 0.166667h;

DOI:10.1016/j.apcata.2012.06.003

upstream raw materials:

limonene.

α-pinene epoxide

D-limonene

1α-hydroxy-2β-phenylseleno-trans-p-menth-8-ene

Downstream raw materials:

1-acetoxy-trans-p-mentha-2,8-diene

abn-cannabidiol

cannabidiol

tetrahydrocannabinol

Refernces

• 1、 Park, Chan Yi,Kim, Young Joon,Lim, Hyo Jin,Park, Jeong Hyeon,Kim, Mi Jin,Seo, Seung Woo,Park, Chan Pil. "Continuous flow photooxygenation of monoterpenes". . p. 4233 - 4237. Retrieved 2015/02/19.
• 2、 You, Kuiyi,Yin, Dulin,Mao, Liqiu,Liu, Pingle,Luo, He'An. "Selective photosensitized oxidation and its catalytic regulation of monoterpene with molecular oxygen in different reaction media". experimental part. p. 321 - 325. Retrieved 2011/10/13.