3,7-bis(dimethylamine)phenothiazonium

Base Information

• Chemical Name: 3,7-bis(dimethylamine)phenothiazonium
• CAS No.: 807306-71-4
• Molecular Formula: C₁₆H₁₈N₃S
• Molecular Weight: 284.405
• Mol file: 807306-71-4.mol

Synonyms:3,7-bis(dimethylamine)phenothiazonium

Chemical Property of 3,7-bis(dimethylamine)phenothiazonium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,7-bis(dimethylamine)phenothiazonium

There total 10 articles about 3,7-bis(dimethylamine)phenothiazonium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methylene blue (152071-32-4,105504-42-5,121067-62-7,12262-49-6,167498-52-4,6476-03-5,97130-83-1) → cyclohexa-3,5-diene-1,2,4-triol + 5-amino-2-hydroxybenzenesulfonic acid (2835-04-3) + 3,7-diamino-10H-phenothiazine 5-oxide + 3,7-bis(dimethylamino)-10H-phenothiazine 5-oxide + 3,7-bis(methyl amino)-10H-phenothiazine 5-oxide + C8H13NO2 + 3,7-bis(dimethylamine)phenothiazonium (807306-71-4) + Azure B (29260-45-5) + 3-aminobenzenesulfonic acid (121-47-1) + phenol (108-95-2,27073-41-2)

Guidance literature:

With Cu_0.04Ni_0.96MoO₄; In water; for 3h; Reagent/catalyst; Irradiation;

DOI:10.1016/j.jphotochem.2017.08.004

Reference yield:

methylene blue (152071-32-4,105504-42-5,121067-62-7,12262-49-6,167498-52-4,6476-03-5,97130-83-1) + benzoyl chloride (98-88-4) → 3,7-bis(dimethylamine)phenothiazonium (807306-71-4) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sodium carbonate; sodium dithionite / dichloromethane; water / 40 °C / Inert atmosphere

1.2: Cooling with ice

2.1: hypochloric acid / aq. phosphate buffer; ethanol / pH 7.2

With sodium dithionite; hypochloric acid; sodium carbonate; In aq. phosphate buffer; ethanol; dichloromethane; water;

DOI:10.1002/anie.201813648

Reference yield:

C42H70O35*C16H18N3S(1+) → 3,7-bis(dimethylamine)phenothiazonium (807306-71-4) + β‐cyclodextrin (7585-39-9)

Guidance literature:

With borax; oxygen; sodium hydroxide; In ethanol; water; at 25 ℃; pH=9.4; Concentration; Equilibrium constant;

DOI:10.1246/bcsj.80.1383

upstream raw materials:

Leuco-Methylenblau

(2E)-but-2-enedioic acid

water

(4-(2-(thiosulfate)-4-(dimethylamino)-phenylimino)-cyclohex-2,5-dienylidene)-N,N-dimethyl ammonium

Downstream raw materials:

2-oxo-propionic acid

Oxalacetic acid

imidazole-4-carboxamide

Leuco-Methylenblau

Refernces

• 1、 Ray, Schindra Kumar,Dhakal, Dipesh,Kshetri, Yuwaraj K.,Lee, Soo Wohn. "Cu-α-NiMoO4 photocatalyst for degradation of Methylene blue with pathways and antibacterial performance". . p. 18 - 32. Retrieved 2017/08/22.
• 2、 Matsumoto, Takeshi,Liu, Yingjin,Sueishi, Yoshimi,Yamamoto, Shunzo. "Effects of ionic surfactants and cyclodextrins on hydride-transfer reaction of l-Benzyl-l,4-dihydronicotinamide with methylene blue". experimental part. p. 1383 - 1390. Retrieved 2009/06/19.