4-oxo-2,2,4-triphenylbutanoic acid

Base Information

• Chemical Name: 4-oxo-2,2,4-triphenylbutanoic acid
• CAS No.: 90267-02-0
• Molecular Formula: C₂₂H₁₈O₃
• Molecular Weight: 330.383
• Mol file: 90267-02-0.mol

Synonyms:4-oxo-2,2,4-triphenylbutanoic acid

Chemical Property of 4-oxo-2,2,4-triphenylbutanoic acid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-oxo-2,2,4-triphenylbutanoic acid

There total 6 articles about 4-oxo-2,2,4-triphenylbutanoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

3,3,5-triphenyl-2(3H)-furanone (2313-03-3) → 1,3,3-triphenylprop-2-en-1-one (849-01-4) + 4-oxo-2,2,4-triphenylbutanoic acid (90267-02-0) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

With potassium superoxide; 18-crown-6 ether; In benzene; for 24h;

Reference yield:

1,3,3-triphenylprop-2-en-1-one (849-01-4) → 1,3,3-triphenylpropan-1-one (606-86-0) + 4-oxo-2,2,4-triphenylbutanoic acid (90267-02-0)

Guidance literature:

With carbon dioxide; In acetonitrile; at 5 - 10 ℃; Further byproducts given; electrolyses at -2.10 V and 2.0 F/mol;

DOI:10.1246/bcsj.57.611

Reference yield:

carbon dioxide (124-38-9,18923-20-1) + 1,3,3-triphenylprop-2-en-1-one (849-01-4) → 1,3,3-triphenylpropan-1-one (606-86-0) + 4-oxo-2,2,4-triphenylbutanoic acid (90267-02-0)

Guidance literature:

In acetonitrile; at 5 - 10 ℃; Further byproducts given; electrolyses at -2.10 V and 2.0 F/mol;

DOI:10.1246/bcsj.57.611

upstream raw materials:

3,3,5-triphenyl-2(3H)-furanone

carbon dioxide

1,3,3-triphenylprop-2-en-1-one

Downstream raw materials:

3,3,5-triphenyl-2(3H)-furanone

Refernces

• 1、 Pandey, Bipin,Tikare, Ravindra K.,Muneer, Mohammed,Kamat, Prashant V.,George, Manapurathu V.. "Electron Transfer Reactions. Reaction of Furanones and Bifurandiones with Potassium and Oxygen". . p. 917 - 928. Retrieved 2007/10/02.