2,2-Bis(hydroxymethyl)butyl methacrylate

Base Information

• Chemical Name: 2,2-Bis(hydroxymethyl)butyl methacrylate
• CAS No.: 7024-09-1
• Deprecated CAS: 89173-61-5
• Molecular Formula: C10H18 O4
• Molecular Weight: 202.251
• European Community (EC) Number: 230-305-6
• DSSTox Substance ID: DTXSID0064545
• Nikkaji Number: J25.103H
• Wikidata: Q81991639
• Mol file: 7024-09-1.mol

Synonyms:Trimethylolpropane monomethacrylate;7024-09-1;2,2-Bis(hydroxymethyl)butyl methacrylate;SCHEMBL30451;trimethylolpropane methacrylate;DTXSID0064545;EINECS 230-305-6;2-Propenoic acid, 2-methyl-, 2,2-bis(hydroxymethyl)butyl ester

Chemical Property of 2,2-Bis(hydroxymethyl)butyl methacrylate

Chemical Property:

• Vapor Pressure: 5.62E-06mmHg at 25°C
• Boiling Point: 340.6°C at 760 mmHg
• Flash Point: 128.8°C
• PSA: 66.76000
• Density: 1.081g/cm³
• LogP: 0.48670
• XLogP3: 0.7
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 7
• Exact Mass: 202.12050905
• Heavy Atom Count: 14
• Complexity: 206

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC(CO)(CO)COC(=O)C(=C)C

Technology Process of 2,2-Bis(hydroxymethyl)butyl methacrylate

There total 3 articles about 2,2-Bis(hydroxymethyl)butyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1,1-tri(hydroxymethyl)propane (77-99-6) + poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) → dimethacrylate trimethylolpropane (19727-16-3) + 2,2-bis(hydroxymethyl)butyl methacrylate (7024-09-1)

Guidance literature:

With toluene-4-sulfonic acid; 4-methoxy-phenol; at 80 ℃; for 15h; Temperature;

Reference yield:

1,1,1-tri(hydroxymethyl)propane (77-99-6) + Methacryloyl chloride (920-46-7,26937-45-1) → 2,2-bis(hydroxymethyl)butyl methacrylate (7024-09-1)

Guidance literature:

With triethylamine; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 3h; Inert atmosphere;

Reference yield:

→ 2,2-bis(hydroxymethyl)butyl methacrylate (7024-09-1)

Guidance literature:

upstream raw materials:

1,1,1-tri(hydroxymethyl)propane

Methacryloyl chloride

poly(methacrylic acid)

Refernces

• 1、 -. "Method for separating partial (meth)acrylated polyols and urethane-based materials functionalized with (meth)acrylate produced by the partial (meth)acrylated polyols". Paragraph 0091; 0092; 0094; 0095; 0097; 0098. . Retrieved 2020/02/07.
• 2、 -. "Chromene compound". . . Retrieved 2008/06/13.