Technology Process of benzyl 1-(methoxycarbonyl)-2-(4-methoxyphenylamino)-2-(4-nitrophenyl)-1-phenylethylcarbamate
There total 1 articles about benzyl 1-(methoxycarbonyl)-2-(4-methoxyphenylamino)-2-(4-nitrophenyl)-1-phenylethylcarbamate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
rhodium(II) acetate dimer; L-Tartaric acid; (S)-3,3'-bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate;
In
toluene;
at -20 ℃;
for 8h;
optical yield given as %ee;
enantioselective reaction;
Inert atmosphere;
Molecular sieve;
DOI:10.1021/ja201589k
