4,8-Dimethyldecanal

Base Information

• Chemical Name: 4,8-Dimethyldecanal
• CAS No.: 75983-36-7
• Molecular Formula: C12H24 O
• Molecular Weight: 184.322
• Hs Code.: 2912190090
• European Community (EC) Number: 278-356-3
• DSSTox Substance ID: DTXSID60997341
• Nikkaji Number: J319.162A
• Metabolomics Workbench ID: 3545
• Mol file: 75983-36-7.mol

Synonyms:4,8-dimethyldecanal;DMD cpd

Chemical Property of 4,8-Dimethyldecanal

Chemical Property:

• Vapor Pressure: 0.0498mmHg at 25°C
• Boiling Point: 235.5°C at 760 mmHg
• Flash Point: 102.1°C
• PSA: 17.07000
• Density: 0.82g/cm³
• LogP: 3.81800
• XLogP3: 4.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 8
• Exact Mass: 184.182715385
• Heavy Atom Count: 13
• Complexity: 120

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC(C)CCCC(C)CCC=O

Technology Process of 4,8-Dimethyldecanal

There total 69 articles about 4,8-Dimethyldecanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

4,8-dimethyl-1,1-dimethoxydecane (106445-80-1) → 4,8-dimethyldecan-1-al (75983-36-7)

Guidance literature:

With water; pyridinium p-toluenesulfonate; In acetone; Heating;

Reference yield: 73.0%

2,6,10-trimethyldodecane-2,3-diol (114088-43-6) → 4,8-dimethyldecan-1-al (75983-36-7)

Guidance literature:

With periodic acid dihydrate; In tetrahydrofuran; at 0 - 5 ℃; for 0.333333h;

DOI:10.1016/j.tet.2016.06.033

Reference yield: 68.0%

4,8-Dimethyldecan-1-ol (28339-05-1) → 4,8-dimethyldecan-1-al (75983-36-7)

Guidance literature:

With pyridinium chlorochromate; In dichloromethane; for 1h; Ambient temperature;

DOI:10.1007/BF00629769

upstream raw materials:

4,8-Dimethyldecan-1-ol

(6R/S,10R/S)-2,6,10-trimethyl-2-dodecene

4,8-dimethyl-1,1-dimethoxydecane

1-bromo-3,7-dimethylnonane

Downstream raw materials:

4(RS),8(S)-dimethyldecanal dimethyl acetal

Refernces

• 1、 Mori, Kenji,Yang, Chang Yeol. "Pheromone synthesis. Part 259: Synthesis of seven methyl-branched hydrocarbons as the pheromone candidates for female Korean apricot wasp, Eurytoma maslovskii". . p. 4593 - 4607. Retrieved 2016/07/07.
• 2、 Kovalev, B. G.,Nasser, Fadel Ahmed,Sorochinskaya, A. M.. "A CONVENIENT SYNTHESIS OF RACEMIC 4,8-DIMETHYLDECANAL, THE AGGREGATION PHEROMONE OF Tribolium castaneum AND Tribolium confusum". . p. 569 - 571. Retrieved 2007/10/02.