SALICYLIDENEANILINE

Base Information

• Chemical Name: SALICYLIDENEANILINE
• CAS No.: 779-84-0
• Molecular Formula: C13H11 N O
• Molecular Weight: 197.236
• Hs Code.: 2925290090
• Mol file: 779-84-0.mol

Synonyms:Phenol,o-(N-phenylformimidoyl)- (6CI,8CI); o-Cresol, a-phenylimino- (4CI); (Salicylideneamino)benzene;2-Hydroxybenzalaniline; 2-[(Phenylimino)methyl]phenol; BAW; Benzenamine,N-[(2-hydroxyphenyl)methylene]-; GBR 11840; N-(2-Hydroxybenzal)aniline;N-(2-Hydroxybenzylidene)aniline; N-(o-Hydroxybenzylidene)aniline;N-Phenylsalicylaldimine; N-Phenylsalicylideneimine; N-Phenylsalicylidenimine;N-Salicylideneaniline; N-Salicylidenephenylamine;N-[(2-Hydroxyphenyl)methylene]phenylamine; NSC 14880; NSC 68443; Salicylalanil; Salicylalaniline; Salicylideneanil; Salicylideneaniline

Chemical Property of SALICYLIDENEANILINE

Chemical Property:

• Appearance/Colour: yellow crystalline powder
• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 49-53 °C(lit.)
• Refractive Index: 1.6050 (estimate)
• Boiling Point: 151 °C / 2mmHg
• PKA: 8.47±0.30(Predicted)
• Flash Point: >230 °F
• PSA: 32.59000
• Density: 1.056g/cm³
• LogP: 3.14280
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• Solubility.: almost transparency in Methanol

Purity/Quality:

98%,99%, ^*data from raw suppliers

N-Salicylideneaniline ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 37/39-26

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of SALICYLIDENEANILINE

There total 46 articles about SALICYLIDENEANILINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

salicylaldehyde (90-02-8) + aniline (62-53-3) → N-phenylsalicylaldimine (779-84-0)

Guidance literature:

at 50 ℃; for 4h;

DOI:10.1002/pola.26754

Reference yield: 94.0%

salicylaldehyde (90-02-8) + phenyl isocyanate (103-71-9) → N-phenylsalicylaldimine (779-84-0)

Guidance literature:

salicylaldehyde; phenyl isocyanate; With tetrabutoxytitanium; In tetrahydrofuran; at 20 ℃; for 48h; Inert atmosphere;

With water; In tetrahydrofuran; Inert atmosphere;

DOI:10.1016/j.jorganchem.2009.10.044

Reference yield: 92.0%

salicylic alcohol (90-01-7) + aniline (62-53-3) → N-phenylsalicylaldimine (779-84-0)

Guidance literature:

salicylic alcohol; With tert.-butylhydroperoxide; Cu₂(bbda)_0.5(Hbbda)_1.5(OAc)_1.5.8H₂O; In neat (no solvent); at 40 ℃;

aniline; In neat (no solvent); at 20 ℃;

DOI:10.1002/aoc.5965

upstream raw materials:

salicylaldehyde

aniline

N-(salicylidene)aniline N-oxide

flavan

Downstream raw materials:

N-phenyl-2-oxochromene-3-carboxamide

anilino-(2-hydroxy-phenyl)-acetonitrile

N³-phenyl-N²-salicylidene-benzofuran-2,3-diyldiamine

acridine

Refernces

• 1、 Aidi,Barkat. "Solvent extraction of copper(II) from sulfate medium with N -(2-hydroxybenzylidene)aniline". . p. 4136 - 4144. Retrieved 2010.
• 2、 Kumar, Manoj,Anjum, Afreen,Jaiswal, Nitesh,Dubey, Raj Kumar. "Synthesis, spectral studies and DFT calculation of copper(II) complexes with mixed ligands". . p. 1679 - 1684. Retrieved 2018.
• 3、 Namli, Hilmi,Turhan, Onur. "Background defining during the imine formation reaction in FT-IR liquid cell". . p. 93 - 100. Retrieved 2006.
• 4、 Ren, Kui,Shang, Xuefang,Fu, Jiajia,Zhao, Peipei,Zhang, Jinlian. "Copper complex based on 2-(phenylimino-methyl)-phenol as a high selective fluoresencent probe for hydrogen sulfide". . p. 99 - 105. Retrieved 2016.
• 5、 Belikov, Mikhail Yu.,Ievlev, Mikhail Yu.,Bardasov, Ivan N.. "A novel water-soluble multicolor halo- And photochromic switching system based on a nitrile-rich acceptor". supporting information. p. 10287 - 10295. Retrieved 2021/06/18.
• 6、 Ghamari Kargar, Pouya,Ravanjamjah, Asiye,Bagherzade, Ghodsieh. "A novel water-dispersible and magnetically recyclable nickel nanoparticles for the one-pot reduction-Schiff base condensation of nitroarenes in pure water". . p. 1916 - 1933. Retrieved 2021/07/10.