Copper glycinate

Base Information

• Chemical Name: Copper glycinate
• CAS No.: 13479-54-4
• Deprecated CAS: 142-51-8,5789-40-2,1608467-77-1
• Molecular Formula: C₄H₈CuN₂O₄
• Molecular Weight: 211.665
• Hs Code.: 2931900090
• European Community (EC) Number: 236-783-2,251-238-9
• UNII: 68VAV8QID7
• DSSTox Substance ID: DTXSID40893690
• Nikkaji Number: J8.121C
• Wikipedia: Copper(II)_glycinate
• Wikidata: Q17377051
• NCI Thesaurus Code: C83639
• Mol file: 13479-54-4.mol

Synonyms:bis(glycinato)copper(II);copper glycinate;copper(II) bisglycinate;cupric glycinate;cupric glycinate, (SP-4-1)-isomer

Chemical Property of Copper glycinate

Chemical Property:

• Vapor Pressure: 0.0123mmHg at 25°C
• Melting Point: 1170 °C
• Boiling Point: 240.9 °C at 760 mmHg
• Flash Point: 99.5 °C
• PSA: 104.64000
• Density: 4.39
• LogP: -0.69670
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• Water Solubility.: soluble H2O, slightly soluble alcohol [MER06]
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 210.978004
• Heavy Atom Count: 11
• Complexity: 37.4

Purity/Quality:

99% ^*data from raw suppliers

Bis(2-aminoacetoxy)copper ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi,T
• Hazard Codes: Xi,T

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(=O)[O-])N.C(C(=O)[O-])N.[Cu+2]
• Uses: Catalyst for rapid biochemical assimilation of iron, electroplating baths, photometric analysis, feed additive.

Technology Process of Copper glycinate

There total 25 articles about Copper glycinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

copper(II) hexafluoro-2,4-pentanedionate + glycine (56-40-6,18875-39-3,25718-94-9) → copper(II) glycinate (10170-99-7,13479-54-4,943407-03-2,10171-08-1,1091630-81-7) + aquabis(hexafluoroacetylacetonato)copper(II)

Guidance literature:

In methanol; inert atmosphere; equimolar amts., stirring at room temp. overnight (pptn.); collection (filtration), drying (vac.);

Reference yield:

copper(II) carbonate + glycine (56-40-6,18875-39-3,25718-94-9) → copper(II) glycinate (10170-99-7,13479-54-4,943407-03-2,10171-08-1,1091630-81-7)

Guidance literature:

copper(II) carbonate; glycine; In water; for 2h;

With citric acid; In water;

Reference yield:

copper(II) hydroxide + glycine (56-40-6,18875-39-3,25718-94-9) → copper(II) glycinate (10170-99-7,13479-54-4,943407-03-2,10171-08-1,1091630-81-7)

Guidance literature:

In ethanol; for 5h; Heating / reflux;

upstream raw materials:

glycine

copper

calcium bisglycinate

copper(II) sulfate

Downstream raw materials:

trans-bis(glycinato)copper(II)

[Cu(N-methyl-5,10,15,20-tetraphenylporphine)]⁽¹⁺⁾

(tetraphenylporphyrin)copper(II)

Refernces

• 1、 Berestova, Tatyana V.,Kuzina, Lyudmila G.,Amineva, Natalya A.,Faizrakhmanov, Ilshat S.,Massalimov, Ismail A.,Mustafin, Akhat G.. "ATR-FTIR spectroscopic investigation of the cis- and trans-bis-(α-amino acids) copper(II) complexes". . p. 260 - 266. Retrieved 2017/03/09.
• 2、 Nashalian, Ossanna,Yaylayan, Varoujan A.. "Thermally induced oxidative decarboxylation of copper complexes of amino acids and formation of strecker aldehyde". . p. 8518 - 8523. Retrieved 2014/11/26.