methyl α-D-lyxopyranoside

Base Information

• Chemical Name: methyl α-D-lyxopyranoside
• CAS No.: 131233-91-5
• Molecular Formula: C₆H₁₂O₅
• Molecular Weight: 164.158
• Mol file: 131233-91-5.mol

Synonyms:methyl α-D-lyxopyranoside

Chemical Property of methyl α-D-lyxopyranoside

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl α-D-lyxopyranoside

There total 113 articles about methyl α-D-lyxopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.4%

methanol (67-56-1) + L-(+)-arabinose (87-72-9,608-45-7,608-46-8,608-47-9,2460-44-8,6748-95-4,6763-34-4,7261-26-9,7283-06-9,7283-07-0,7296-55-1,7296-56-2,7296-58-4,7296-59-5,7296-60-8,7296-61-9,7296-62-0,7322-30-7,10257-31-5,10257-32-6,10257-33-7,10257-34-8,10257-35-9,19982-83-3,20242-88-0,28697-53-2,36562-42-2,41546-41-2,89299-64-9,107655-34-5,115794-06-4,115794-07-5,130550-15-1,130606-21-2) → methyl β-L-arabinopyranoside (91-09-8,612-05-5,1825-00-9,2500-78-9,3867-83-2,3945-28-6,5328-63-2,6206-67-3,6207-01-8,6207-03-0,7404-24-2,14703-09-4,17289-61-1,18449-76-8,33509-64-7,36793-06-3,41897-31-8,41897-32-9,41897-33-0,41897-34-1,41897-37-4,41897-38-5,41897-39-6,53448-52-5,65137-86-2,89615-04-3,89615-05-4,131233-91-5)

Guidance literature:

With hydrogenchloride; for 6h; Reflux;

DOI:10.1080/00397911.2010.520402

Reference yield: 73.2%

methanol (67-56-1) + L-arabinose (5328-37-0) → methyl β-L-arabinopyranoside (91-09-8,612-05-5,1825-00-9,2500-78-9,3867-83-2,3945-28-6,5328-63-2,6206-67-3,6207-01-8,6207-03-0,7404-24-2,14703-09-4,17289-61-1,18449-76-8,33509-64-7,36793-06-3,41897-31-8,41897-32-9,41897-33-0,41897-34-1,41897-37-4,41897-38-5,41897-39-6,53448-52-5,65137-86-2,89615-04-3,89615-05-4,131233-91-5)

Guidance literature:

With hydrogenchloride; at 80 ℃; for 3h;

DOI:10.1248/cpb.47.1717

Reference yield: 64.6%

methanol (67-56-1) + trigoneoside VI → methyl D-glucopyranoside (97-30-3,617-04-9,709-50-2,1824-94-8,2152-78-5,3396-99-4,6819-48-3,18469-06-2,20550-04-3,22277-65-2,29411-57-2,35437-40-2,35437-43-5,36191-11-4,36191-12-5,39598-79-3,39598-80-6,39598-89-5,51023-63-3,51223-62-2,51224-38-5,51224-39-6,51224-40-9,51224-41-0,51819-81-9,51819-82-0,51819-83-1,56688-81-4,62279-53-2,64281-79-4,64281-80-7,64912-19-2,66101-73-3,78184-90-4,84368-39-8,84368-40-1,84368-41-2,92142-37-5,93302-26-2,103421-28-9,115794-08-6,3149-68-6) + methyl xyloside (91-09-8,612-05-5,1825-00-9,2500-78-9,3867-83-2,3945-28-6,5328-63-2,6206-67-3,6207-01-8,6207-03-0,7404-24-2,17289-61-1,18449-76-8,33509-64-7,36793-06-3,41897-31-8,41897-32-9,41897-33-0,41897-34-1,41897-37-4,41897-38-5,41897-39-6,53448-52-5,65137-86-2,89615-04-3,89615-05-4,131233-91-5,14703-09-4) + methyl L-rhamnopyranoside (1128-40-1,1198-82-9,2592-55-4,5155-43-1,6340-52-9,10503-91-0,14009-07-5,14687-15-1,14917-55-6,15814-59-2,24332-98-7,34299-65-5,42214-00-6,42214-11-9,57783-34-3,57783-36-5,57783-38-7,57783-40-1,57783-42-3,58525-46-5,58525-47-6,58525-48-7,62182-01-8,62182-02-9,65310-00-1,65941-62-0,68069-80-7,71116-57-9,72274-54-5,72274-55-6,73036-22-3,83198-64-5,85505-15-3,102517-74-8,109718-80-1,109718-81-2,125280-09-3,129172-95-8,63864-94-8) + spirosta-5,25(27)-diene-3β-ol

Guidance literature:

With hydrogenchloride; for 2.5h; Product distribution; Heating;

DOI:10.3987/COM-97-S(N)52

upstream raw materials:

2-O-(methylsulfonyl)-1,3,5-tri-O-benzoyl-α-D-ribofuranose

methanol

dichloromethane

sodium methylate

Downstream raw materials:

methyl O²,O⁴-phenylboranediyl-β-D-ribopyranoside

Methyl-β-L-arabinosid-<3,4-phenylboronat>

(R)-2-methoxy-2,2'-oxy-bis-acetaldehyde

(S)-2-methoxy-2,2'-oxy-bis-acetaldehyde

Refernces

• 1、 Paradowska, Katarzyna,Gubica, Tomasz,Temeriusz, Andrzej,Cyranski, Michal K.,Wawer, Iwona. "13C CP MAS NMR and crystal structure of methyl glycopyranosides". . p. 2299 - 2307. Retrieved 2008.
• 2、 Cadotte et al.. "-". . p. 1501,1503. Retrieved 1952.
• 3、 Rychlik,Schieberle. "Synthesis of 13C-Labeled Patulin [4-Hydroxy-4H-furo[3,2-c]pyran-2(6H)-one] to Be Used as Internal Standard in a Stable Isotope Dilution Assay". . p. 5163 - 5169. Retrieved 1998.
• 4、 Weinges, Klaus,Haremsa, Sylke,Maurer, Wolfgang. "The Mitsunobu reaction on methyl glycosides as alcohol component". . p. 453 - 458. Retrieved 1987.
• 5、 Prabhakar, Sunchu,Lemiègre, Lo?c,Benvegnu, Thierry,Hotha, Srinivas,Ferrières, Vincent,Legentil, Laurent. "Efficient isomerization of methyl arabinofuranosides into corresponding arabinopyranosides in presence of pyridine". . p. 63 - 66. Retrieved 2016.
• 6、 Iglesias, Jose,Melero, Juan A.,Morales, Gabriel,Paniagua, Marta,Hernández, Blanca. "Dehydration of Xylose to Furfural in Alcohol Media in the Presence of Solid Acid Catalysts". . p. 2089 - 2099. Retrieved 2016.
• 7、 Buchanan,Edgar. "-". . p. 289,301. Retrieved 1976.
• 8、 De Graef, Steff,Gadakh, Bharat,Nautiyal, Manesh,Pang, Luping,Strelkov, Sergei V.,Van Aerschot, Arthur,Vondenhoff, Gaston,Weeks, Stephen D.. "Synthesis and structural insights into the binding mode of the albomycin δ1 core and its analogues in complex with their target aminoacyl-tRNA synthetase". . . Retrieved 2020.
• 9、 Smith,Van Cleve. "-". . p. 3159. Retrieved 1955.
• 10、 Hudson. "-". . p. 265,266. Retrieved 1925.