POTASSIUM 2,4,6-TRINITROPHENOLATE

Base Information

• Chemical Name: POTASSIUM 2,4,6-TRINITROPHENOLATE
• CAS No.: 573-83-1
• Molecular Formula: C6H2KNO7
• Molecular Weight: 267.196
• Mol file: 573-83-1.mol

Synonyms:POTASSIUM PICRATE ANHYDROUS;POTASSIUM PICRATE;Picric acid potassium;potassium 2,4,6-trinitrophenoxide;Kaliumpikrat;2,4,6-trinitro-phenol,potassium salt;2,4,6-trinitro-phenopotassiumsalt;

Chemical Property of POTASSIUM 2,4,6-TRINITROPHENOLATE

Chemical Property:

• Vapor Pressure: 0.000514mmHg at 25°C
• Melting Point: 122-123oC
• Boiling Point: 303.6°Cat760mmHg
• Flash Point: 133.9°C
• PSA: 160.52000
• Density: g/cm³
• LogP: 3.12460

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of POTASSIUM 2,4,6-TRINITROPHENOLATE

There total 44 articles about POTASSIUM 2,4,6-TRINITROPHENOLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1-methoxy-2,4,6-trinitrobenzene (606-35-9) → potassium picrate (573-83-1)

Guidance literature:

With potassium iodide; In ethanol; Heating;

DOI:10.1016/0040-4020(96)00201-3

Reference yield: 52.0%

2,4,6-trinitrochlorobenzene (88-88-0) → potassium picrate (573-83-1)

Guidance literature:

With potassium trimethylstannate; In tetrahydrofuran;

Reference yield: 52.0%

picryl fluoride (364-44-3) → potassium picrate (573-83-1)

Guidance literature:

With C₈H₈K₂; In tetrahydrofuran; for 24h; Product distribution; Mechanism; Ambient temperature;

upstream raw materials:

2,4,6-trinitrochlorobenzene

1-(γ-hydroxypropoxy)-2,4,6-trinitrobenzene

picryl fluoride

2,4,6-trinitrophenyl phenyl ether

Downstream raw materials:

C₉H₂N₇O₁₀S^(1-)*K⁽¹⁺⁾

Refernces

• 1、 Li, Ning,Chen, Feng,Shen, Jie,Zhang, Hao,Wang, Tianxiang,Ye, Ruijuan,Li, Tianhu,Loh, Teck Peng,Yang, Yi Yan,Zeng, Huaqiang. "Buckyball-Based Spherical Display of Crown Ethers for de Novo Custom Design of Ion Transport Selectivity". supporting information. p. 21082 - 21090. Retrieved 2020/12/21.
• 2、 Marcos, Paula M.,Ascenso, José R.,Segurado, Manuel A.P.,Bernardino, Raul J.,Cragg, Peter J.. "Synthesis, binding properties and theoretical studies of p-tert-butylhexahomotrioxacalix[3]arene tri(adamantyl)ketone with alkali, alkaline earth, transition, heavy metal and lanthanide cations". experimental part. p. 496 - 503. Retrieved 2009/04/07.